Heat pipe heat exchangers (HPHEXs) are widely used in various industries. In this paper, a novel model of a liquid–liquid heat pipe heat exchanger in a countercurrent manner is established by considering the evaporation and condensation thermal resistances inside the heat pipes (HPs). The discrete method is added to the HPHEX model to determine the thermal resistances of the HPs and the temperature change trend of the heat transfer fluid in the HPHEX. The established model is verified by the HPHEX structure and experimental data in the existing literature and demonstrates numerical results that agree with the experimental data to within a 5% error. With the current model, the investigation compares the effectiveness and minimum vapor temperature of the HPHEX with three types of HP diameters, different mass flow rates, and different H* values. For HPs with a diameter of 36 mm, the effectiveness of each is improved by about 0.018 to 0.029 compared to HPs with a diameter of 28 mm. The results show that the current model can predict the temperature change trend of the HPHEX well; in addition, the effects of different structures on the effectiveness and minimum vapor temperature are obtained, which improve the performance of the HPHEX.
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