Quinestrol (QUN), a synthetic estrogen used as an oral contraceptive or emergency contraceptive component, has been shown to be an endocrine-disrupting chemical. To assess the environmental risk of QUN, batch equilibration experiments were conducted to investigate the adsorption–desorption of QUN in five contrasting soils from different areas of China. The leaching properties were also calculated based on the adsorption and degradation data from our previous study with the same soils. The Freundlich and Langmuir models were applied to the sorption–desorption data to examine the affinity towards QUN of the soils, which had varying physical and chemical properties. The K
f
and K
f
des
values of QUN in the tested soils ranged from 3.72 to 20.47 mg
1−n
L
n
kg
−1
and from 1.26 to 7.8 mg
1−n
L
n
kg
−1
, respectively, and
Q
m
ranged from 28.25 to 126.58 mg/kg. The desorption data showed that hysteresis occurred. The K
f
and K
f
des
values of QUN were positively correlated with the soil total organic carbon (OC) and cation exchange capacity (CEC), and it may be due to the content of TOC and CEC exhibited a positive correlation. A low mobility potential of QUN in soils was predicted and verified the adsorption results by the groundwater ubiquity score (GUS) and retardation factor (R
f
).
Conical arrays of polydimethyl siloxane were fabricated by duplicating the morphology of needle tips. The prepared cones have periodic order and regular shape, with the bottom diameter of about 80 μm and height of about 250 μm. Due to their special structure, the conical arrays of polydimethyl siloxane exhibited broadband anti-reflective property. Compared with smooth surface, they could reduce the reflection of incident electromagnetic wave at ultraviolet, visible and near-infrared region. The specular reflectance was lower than 0.75% in the range of 250-2600 nm. The prepared PDMS cones have potential to be applied for antireflective devices. The method was simple for mass production of PDMS cones at low cost.
The adsorption process of Cr (VI) in aqueous solution on activated carbon prepared by wheat straw was investigated to study the effect factors on adsorption properties. adsorption mechanism was discussed. The results showed that the adsorption performance was influenced by dosage, initial concentration and adsorption time. Adsorption reached equilibrium after 100 min at temperature 25°C. The highest removal efficiency can reach 94%. The results indicated that activated carbon as adsorbent can effectively deal with waste water containing (VI).
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