The Ca-doped YBa2Cu3O7−δ/Y2BaCuO5 bulk-textured superconductors were prepared by using the top-seeding melt-textured growth process. Composition analyses were made for such prepared samples. We found that Ca concentration in the YBa2Cu3O7−δ grains decreased along the growing direction; Ca preferred to substitute Y in the YBa2Cu3O7−δ grains, rather than to stay at the grain boundary. The accumulation of extra CuO at the growth front was considered as one of the causes of the inhomogeneous distribution of Ca.