As the problem of shrinkage on wool fabric, the chitosan was applied to solve it in this paper. The volume of retraction bulb and strength were considered to describe the results of anti-shrinkage after the finishing. It shows that great anti-shrinkage is got in this experiment, and the best treatment process is defined as follow: the concentration of chitosan 6g/l, pH 5, 80min, 90°C and bath ratio 1:50.
This paper discussed the influences of plasma processing time and power on wool fibers, the results showed that: after plasma treatment, the surface of the wool fibers occurred varying degrees of physical and chemical etching phenomenon, the wetting property was increased significantly, anti-shrinkage performance was improved. Breaking strength and elongation at fracture were increased; the beginning of dyeing properties and the balance rate were increased.
In order to improve the hydrophobic property of Polyvinylidene fluoride (PVDF) membrane, in this paper nano-silica was modified by silane coupling agent firstly, then the modified nano-silica mixed with fluororesin,crosslinking agent and thickener to prepare the super-hydrophobic surface coating, finally the surface coating was covered on PVDF membrane. The results showed that the contact angle of the modified membrane was 162°and the sliding angle was 4°. The modified membrane was test by SEM and AFM, the surface coating on the PVDF membrane formed micro/nano-meter structure such as lotus leaves surface.
For preparation of an architecture membrane with hydrophobic properties, a method combining supercritical carbon dioxide (scCO2 ) and low temperature plasma treatment was used. The effects of treating time, pressure and temperature in scCO2 fluid on surface hydrophobic property were studied. The results showed that the contact angle of the membrane that was firstly modified by low temperature plasma and then treated in scCO2 fluid was up to 141°from 80°. In addition, the optimal hydrophobic modification conditions in scCO2 were 100°C、25MPa and 6h, and the hydrophobic property of the membrane that treated by plasma improved, the most suitable time was 300s.
The title compound, [Ag(C15H11N4O2S)]n, was synthesized by the reaction of 4-{[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]methyl}benzoic acid (Hptmba) with silver nitrate and triethylamine at room temperature. The asymmetric unit contains one crystallographically independent Ag(I) cation and one ptmba(-) ligand. Each Ag(I) cation is tricoordinated by two carboxylate O atoms and one tetrazole N atom from three different ptmba(-) ligands, displaying a distorted T-shaped geometry. Three Ag(I) cations are linked by tris-monodentate bridging ptmba(-) ligands to form a one-dimensional double chain along the c axis, which is further consolidated by an intrachain π-π contact with an offset face-to-face distance of 4.176 (3) Å between the centroids of two adjacent aromatic rings in neighbouring benzoate groups. The one-dimensional chains are linked into a three-dimensional supramolecular framework by additional π-π interchain interactions, viz. of 3.753 (3) Å between two phenyl substituents of the tetrazole rings and of 4.326 (2) Å between a benzoate ring and a tetrazole ring. Thermogravimetric analysis and the fluorescence spectrum of the title compound reveal its good thermal stability and a strong green luminescence at room temperature.
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