Marine biofouling profoundly influences marine industries and activities. It slows the speed and increases the fuel consumption of ships, corrodes offshore platforms, and blocks seawater pipelines. The most effective and economical antifouling approach uses coatings. Fouling-release coatings (FRCs) with low surface free energy and high elasticity weakly adhere to marine organisms, so they can be readily removed by the water shear force. FRCs have attracted increasing interest because they are biocide-free and hence ecofriendly. However, traditional silicone-based FRCs have weak adhesion to substrates, low mechanical strength, and low fouling resistance, limiting their applications. In recent years, many attempts have been made to improve their mechanical properties and fouling resistance. This review deals with the progress in the construction of high-performance silicone-based fouling-release surfaces.
Dynamic surface antifouling (DSA) using degradable polymers with excellent antifouling performance and mechanical properties is an effective and promising strategy.
Self-repairing silicone coatings with controlled release of organic antifoulants have excellent antifouling/fouling release performance even under static conditions.
Four unusual indole-terpenoids, penerpenes A−D (1−4), along with two known ones paxilline (5) and emindole SB (6), were isolated from the marine-derived fungus Penicillium sp. KFD28. The absolute structures of 1−4 were elucidated on the basis of spectroscopic data and ECD spectra analysis along with quantum ECD calculations. Compounds 1 and 2 showed potent inhibitory activity toward protein tyrosine phosphatases (PTP1B and TCPTP). Plausible biosynthetic pathways of compounds 1−4 are proposed.
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