The stringent safety
and sustainability requirements for electrolytes used in lithium batteries
have led to significant research efforts into alternative materials.
Here, a quasi-solid electrolyte based on biodegradable bacterial cellulose
(BC) was successfully synthesized via a simple ball milling method.
The BC provides plenty of sites for the attachment of ionic liquid
electrolytes (ILEs) as well as ion transport channels. Moreover, the
O–H groups contained in the BC molecular chains interact with
anions in ILEs to form hydrogen bonds, which promotes the dissociation
of the lithium salts. The prepared electrolytes (BC-ILEs) have good
thermal stability with a decomposition temperature exceeding 300 °C
and high ionic conductivities. The Li/BC-ILE/LiFePO4 battery
exhibits remarkable electrochemical performance. More importantly,
the results of the Fehling test verify that the electrolyte can be
degraded by cellulase. The quasi-solid electrolyte broadens the range
of electrolytes for lithium batteries and provides new avenues to
explore safe and eco-friendly materials.
Internal flow field ablation is an important issue in thermal protection materials for rocket engines and hypersonic vehicles. In this paper, a new multiphase flow ablation test system, with an Al2O3 particle delivery device based on an oxygen-kerosene liquid rocket engine, is designed and manufactured. A general variable-precision modular system simulation method is proposed to analyze the dynamic characteristics of the system. In addition, a unique internal flow field ablation test was performed on the 4D C/C composite simulating the working conditions of the SRM. The results show that the system can provide a wide temperature range (756~3565 K) and pressure range (0.2~4.2 MPa). The multi-disciplinary dynamic variable-precision system simulation method is helpful for more accurate design and test analysis, and the maximum error is less than 5%. The ablation tests show that the line ablation rate of the C/C composite nozzle at 3380 K and 1 MPa is 0.053 mm/s, verifying the combined effect of thermochemical and mechanical ablation. The ablation environment is controllable, which provides an effective way for the ablation test of thermal protection materials. In addition, the variable-precision dynamic simulation method has important reference value for the system design related to liquid rocket engine.
For the research demand of reusable LOX/kerosene variable thrust liquid rocket engine, a test system with electric displacement pumps is designed and a multidisciplinary modular dynamic simulation method based on AMESim platform is used to analyze the system. The method comprehensively considers the characteristics of complex components in the engine and realizes the fast module assembly and variable step size solution. Considering the combustion model of thrust chamber, the positive displacement pump model with complex leakage channels, and the cooling jacket heat transfer model, the component dynamic equations are deduced and the final model simulation results reveal that the system has a smooth ignition, stage turning, and shutdown process. The thrust can reach 6900 N in high working condition and the variable thrust ratio is 5 : 1. The dynamic characteristics of the system show that the performance error of main pump components is less than 5%, the maximum average temperature rise of the thrust chamber coolant is about 28°C, and the time of stage adjustment is within 300 ms, which mean the overall design of the system is reasonable. Although the accumulation of LOX before kerosene injection can adversely affect the temperature of the thrust chamber, large pressure pulses do not occur due to the ignitor’s duty flame. Moreover, the pintle injectors based on PID control can effectively stabilize the pressure drop at lower conditions. The system and the simulation method provide important support for the actual engine test and the general LRE dynamic characteristics analysis.
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