Group‐10 transition metal dichalcogenides (TMDs) with distinct optical and tunable electrical properties have exhibited great potential for various optoelectronic applications. Herein, a self‐powered photodetector is developed with broadband response ranging from deep ultraviolet to near‐infrared by combining FA1−xCsxPbI3 perovskite with PdSe2 layer, a newly discovered TMDs material. Optoelectronic characterization reveals that the as‐assembled PdSe2/perovskite Schottky junction is sensitive to light illumination ranging from 200 to 1550 nm, with the highest sensitivity centered at ≈800 nm. The device also shows a large on/off ratio of ≈104, a high responsivity (R) of 313 mA W−1, a decent specific detectivity (D*) of ≈1013 Jones, and a rapid response speed of 3.5/4 µs. These figures of merit are comparable with or much better than most of the previously reported perovskite detectors. In addition, the PdSe2/perovskite device exhibits obvious sensitivity to polarized light, with a polarization sensitivity of 6.04. Finally, the PdSe2/perovskite detector can readily record five “P,” “O,” “L,” “Y,” and “U” images sequentially produced by 808 nm. These results suggest that the present PdSe2/perovskite Schottky junction photodetectors may be useful for assembly of optoelectronic system applications in near future.
Food production in green crops is severely limited by low activity and poor specificity of D-ribulose-1,5-bisphosphate carboxylase/oxygenase (RuBisCO) in natural photosynthesis (NPS). This work presents a scientific solution to overcome this problem by immobilizing RuBisCO into a microfluidic reactor, which demonstrates a continuous production of glucose precursor at 13.8 μmol g
−1
RuBisCO min
−1
from CO
2
and ribulose-1,5-bisphosphate. Experiments show that the RuBisCO immobilization significantly enhances enzyme stabilities (7.2 folds in storage stability, 6.7 folds in thermal stability), and also improves the reusability (90.4% activity retained after 5 cycles of reuse and 78.5% after 10 cycles). This work mimics the NPS pathway with scalable microreactors for continuous synthesis of glucose precursor using very small amount of RuBisCO. Although still far from industrial production, this work demonstrates artificial synthesis of basic food materials by replicating the light-independent reactions of NPS, which may hold the key to food crisis relief and future space colonization.
As a type of flexible electronics, wearable heaters have attracted broad attention because of their giant potential market value, such as for use in wearable thermotherapy. Wearable heaters are required to simultaneously possess high stretchability and dynamic stability, in order to realize joints or muscles thermotherapy during exercising. Here, a high‐performance electrically driven heater using the conductive composite of liquid‐metal (LM) and polydimethylsiloxane (PDMS) is reported, which is patterned as sinusoidal structure by the printing technology of direct ink writing. Because high conductive LM is chosen as the active material, the LM@PDMS stretchable heater possesses high stretchability (>100% strain) and good conductivity (1.81 × 103 S cm−1). It also exhibits superb dynamic stability, due to the 3D conductive network of LM in matrix and the sinusoidal structure of the composite. While being stretched to the strain level of 100%, the heating temperature variation of LM@PDMS stretchable heater is less than 8%. This relatively low temperature variation is several times smaller than that of existing heaters at the same large strain levels. It is demonstrated that the LM@PDMS stretchable heater worn on the knee joint works well during strenuous exercise, thus proving great potential in wearable thermotherapy.
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