Using the ionic liquid [emim][Tf2N] as a physical solvent, it was found by aspen plus simulation that it was possible to attempt to capture CO2 from the flue gas discharged from the coal-fired unit of the power plant. Using the combination of model calculation and experimental determination, the density, isostatic heat capacity, viscosity, vapor pressure, thermal conductivity, surface tension and solubility of [emim][Tf2N] were obtained. Based on the NRTL model, the Henry coefficient and NRTL binary interaction parameters of CO2 dissolved in [emim][Tf2N] were obtained by correlating [emim][Tf2N] with the gas-liquid equilibrium data of CO2. Firstly, the calculated relevant data is imported into Aspen plus, and the whole process model of the ionic liquid absorption process is established. Then the absorption process is optimized according to the temperature distribution in the absorption tower to obtain a new absorption process. Finally, the density, constant pressure heat capacity, surface tension, thermal conductivity, viscosity of [emim][Tf2N] were changed to investigate the effect of ionic liquid properties on process energy consumption, solvent circulation and heat exchanger design.The results showed that based on the composition of the inlet gas stream to the absorbers, CO2 with a capture rate of 90% and a mass purity higher than 99.5% was captured; These results indicate that the [emim][Tf2N] could be used as a physical solvent for CO2 capture from coal-fired units.In addition,The results will provide a theoretical basis for the design of new ionic liquids for CO2 capture.

Oxy-fuel combustion technology is an effective way to reduce CO2 emissions. An ionic liquid [emim][Tf2N] was used to capture the CO2 in flue gas from oxy-fuel combustion plant. The process of the CO2 capture was simulated using Aspen Plus. The results show that when the liquid–gas ratio is 1.55, the volume fraction of CO2 in the exhaust gas is controlled to about 2%. When the desorption pressure is 0.01 MPa, desorption efficiency is 98.2%. Additionally, based on the designability of ionic liquids, a hypothesis on the physical properties of ionic liquids is proposed to evaluate their influence on the absorption process and heat exchanger design. The process evaluation results show that an ionic liquid having a large density, a large thermal conductivity, and a high heat capacity at constant pressure is advantageous. This paper shows that from capture energy consumption and lean circulation, oxy-fuel combustion is a more economical method. Furthermore, it provides a feasible path for the treatment of CO2 in the waste gas of oxy-fuel combustion. Meanwhile, Aspen simulation helps speed up the application of ionic liquids and oxy-fuel combustion. Process evaluation helps in equipment design and selection.