Delivering liquid through the void spaces in porous metals is a daunting challenge for a variety of emerging interface technologies ranging from battery electrodes to evaporation surfaces. Hydraulic transport characteristics of well-ordered porous media are governed by the pore distribution, porosity, and morphology. Much like energy transport in polycrystalline solids, hydraulic transport in semi-ordered porous media is predominantly limited by defects and grain boundaries. Here, we report the wicking performances for porous copper inverse opals having pore diameters from 300 to 1000 nm by measuring the capillary-driven liquid rise. The capillary performance parameter within single crystal domain (Kij/Reff = 10−3 to 10−2 µm) is an order of magnitude greater than the collective polycrystal (Keff/Reff = ~10−5 to 10−3 µm) due to the hydraulic resistances (i.e. grain boundaries between individual grains). Inspired by the heterogeneity found in biological systems, we report that the capillary performance parameter of gradient porous copper (Keff/Reff = ~10−3 µm), comparable to that of single crystals, overcomes hydraulic resistances through providing additional hydraulic routes in three dimensions. The understanding of microscopic liquid transport physics through porous crystals and across grain boundaries will help to pave the way for the spatial design of next-generation heterogeneous porous media.

Self‐assembly continuously gains attention as an excellent method to create novel nanoscale structures with a wide range of applications in photonics, optoelectronics, biomedical engineering, and heat transfer applications. However, self‐assembly is governed by a diversity of complex interparticle forces that cause fabricating defectless large scale (>1 cm) colloidal crystals, or opals, to be a daunting challenge. Despite numerous efforts to find an optimal method that offers the perfect colloidal crystal by minimizing defects, it has been difficult to provide physical interpretations that govern the development of defects such as grain boundaries. This study reports the control over grain domains and intentional defect characteristics that develop during evaporative vertical deposition. The degree of particle crystallinity and evaporation conditions is shown to govern the grain domain characteristics, such as shapes and sizes. In particular, the grains fabricated with 300 and 600 nm sphere diameters can be tuned into single‐column structures exceeding ≈1 mm by elevating heating temperature up to 93 °C. The understanding of self‐assembly physics presented in this work will enable the fabrication of novel self‐assembled structures with high periodicity and offer fundamental groundworks for developing large‐scale crack‐free structures.

No abstract

A recent design approach in creating super-repellent surfaces through slippery surface lubrication offers tremendous liquid-shedding capabilities. Previous investigations have provided significant insights into droplet−lubricant interfacial behaviors that govern antiwetting properties but have often studied using macroscale droplets. Despite drastically different governing characteristics of ultrasmall droplets on slippery lubricated surfaces, little is known about the effects at the micro-and nanoscale. In this investigation, we impregnate a three-dimensionally, well-ordered porous metal architecture with a lubricant to confirm durable slippery surfaces. We then reduce the droplet size to a nanoliter range and experimentally compare the droplet behaviors at different length scales. By experimentally varying the lubricant thickness levels, we also reveal that the effect of lubricant wetting around ultrasmall droplets is intensely magnified, which significantly affects the transient droplet dynamics. Molecular dynamics computations further examine the ultrasmall droplets with varying lubricant levels or pore cut levels at the nanoscale. The combined experimental and computational work provides insights into droplet interfacial phenomena on slippery surfaces from a macroscale to nanoscale perspective.