The composition of giant planets is imprinted by their migration history and the compositional structure of their hosting disks. Studies in recent literature have investigated how the abundances of C and O can constrain the formation pathways of giant planets forming within few tens of au from a star. New ALMA observations, however, suggest planet-forming regions possibly extending to hundreds of au. We explore the implications of these wider formation environments through n-body simulations of growing and migrating giant planets embedded in planetesimal disks, coupled with a compositional model of the protoplanetary disk where volatiles are inherited from the molecular cloud and refractories are calibrated against extrasolar and Solar System data. We find that the C/O ratio provides limited insight on the formation pathways of giant planets that undergo large-scale migration. This limitation can be overcome, however, thanks to nitrogen and sulfur. Jointly using the C/N, N/O, and C/O ratios breaks any degeneracy in the formation and migration tracks of giant planets. The use of elemental ratios normalized to the respective stellar ratios supplies additional information on the nature of giant planets, thanks to the relative volatility of O, C, and N in disks. When the planetary metallicity is dominated by the accretion of solids C/N * > C/O * > N/O * ( * denoting this normalized scale), otherwise N/O * > C/O * > C/N * . The S/N ratio provides an additional independent probe into the metallicity of giant planets and their accretion of solids.

The James Webb Space Telescope (JWST) is expected to revolutionize the field of exoplanets. The broad wavelength coverage and the high sensitivity of its instruments will allow characterization of exoplanetary atmospheres with unprecedented precision. Following the Call for the Cycle 1 Early Release Science Program, the Transiting Exoplanet Community was awarded time to observe several targets, including WASP-43b. The atmosphere of this hot Jupiter has been intensively observed but still harbors some mysteries, especially concerning the day-night temperature gradient, the efficiency of the atmospheric circulation, and the presence of nightside clouds. We will constrain these properties by observing a full orbit of the planet and extracting its spectroscopic phase curve in the 5-12 µm range with JWST/MIRI. To prepare for these observations, we performed an extensive modeling work with various codes: radiative transfer, chemical kinetics, cloud microphysics, global circulation models, JWST simulators, and spectral retrieval. Our JWST simulations show that we should achieve a precision of 210 ppm per 0.1 µm spectral bin on average, which will allow us to measure the variations of the spectrum in longitude and measure the night-side emission spectrum for the first time. If the atmosphere of WASP-43b is clear, our observations will permit us to determine if its atmosphere has an equilibrium or disequilibrium chemical composition, providing eventually the first conclusive evidence of chemical quenching in a hot Jupiter atmosphere. If the atmosphere is cloudy, a careful retrieval analysis will allow us to identify the cloud composition.

We present results from a set of simulations using a fully coupled three-dimensional (3D) chemistry-radiationhydrodynamics model and investigate the effect of transport of chemical species by the large-scale atmospheric flow in hot Jupiter atmospheres. We couple a flexible chemical kinetics scheme to the Met Office Unified Model which enables the study of the interaction of chemistry, radiative transfer and fluid dynamics. We use a newly-released "reduced" chemical network comprising 30 chemical species that has been specifically developed for application in 3D atmosphere models. We simulate the atmospheres of the well-studied hot Jupiters HD 209458b and HD 189733b which both have dayside-nightside temperature contrasts of several hundred Kelvin and superrotating equatorial jets. We find qualitatively quite different chemical structures between the two planets, particularly for methane (CH4), when advection of chemical species is included. Our results show that consideration of 3D chemical transport is vital in understanding the chemical composition of hot Jupiter atmospheres. 3D mixing leads to significant changes in the abundances of absorbing gas-phase species compared with what would be expected by assuming local chemical equilibrium, or from models including 1D -and even 2D -chemical mixing. We find that CH4, carbon dioxide (CO2) and ammonia (NH3) are particularly interesting as 3D mixing of these species leads to prominent signatures of out-of-equilibrium chemistry in the transmission and emission spectra, detectable with near-future instruments.

State of the art spectral retrieval models of exoplanet atmospheres assume constant chemical profiles with altitude. This assumption is justified by the information content of current datasets which do not allow, in most cases, for the molecular abundances as a function of pressure to be constrained.In the context of the next generation of telescopes, a more accurate description of chemical profiles may become crucial to interpret observations and gain new insights into atmospheric physics. We explore here the possibility of retrieving pressure-dependent chemical profiles from transit spectra, without injecting any priors from theoretical chemical models in our retrievals. The "2-layer" parameterisation presented here allows for the independent extraction of molecular abundances above and below a certain atmospheric pressure.By simulating various cases, we demonstrate that this evolution from constant chemical abundances is justified by the information content of spectra provided by future space instruments. Comparisons with traditional retrieval models show that assumptions made on chemical profiles may significantly impact retrieved parameters, such as the atmospheric temperature, and justify the attention we give here to this issue.We find that the 2-layer retrieval accurately captures discontinuities in the vertical chemical profiles, which could be caused by disequilibrium processes -such as photo-chemistry -or the presence of clouds/hazes. The 2-layer retrieval could also help to constrain the composition of clouds and hazes by exploring the correlation between the chemical changes in the gaseous phase and the pressure at which the condensed phase occurs.The 2-layer retrieval presented here therefore represents an important step forward in our ability to constrain theoretical chemical models and cloud/haze composition from the analysis of future observations.

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems1,2. Access to the chemical inventory of an exoplanet requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based3–5 and high-resolution ground-based6–8 facilities. Here we report the medium-resolution (R ≈ 600) transmission spectrum of an exoplanet atmosphere between 3 and 5 μm covering several absorption features for the Saturn-mass exoplanet WASP-39b (ref. 9), obtained with the Near Infrared Spectrograph (NIRSpec) G395H grating of JWST. Our observations achieve 1.46 times photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO2 (28.5σ) and H2O (21.5σ), and identify SO2 as the source of absorption at 4.1 μm (4.8σ). Best-fit atmospheric models range between 3 and 10 times solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO2, underscore the importance of characterizing the chemistry in exoplanet atmospheres and showcase NIRSpec G395H as an excellent mode for time-series observations over this critical wavelength range10.