The conductivity of the
NaClO3‐normalNaCl‐H2Ofalse(lfalse)
system for temperatures above 80°C was investigated. The
NaClO3
concentration ranged from
412 normalto 1354 normalg/1000normalg H2O
and the
normalNaCl
concentration varied from
74 normalto 177 normalg/1000normalg H2O
. Temperature and
NaClO3
concentration were both significant variables in affecting the conductance of the salt solution. Regression analysis was used to determine the coefficients for a series of empirical conductance equations. These model equations used various concentration terms, as square root, linear, square, and logarithmic, and are compared to experimental results. Only two equations are reported and these equations predict the experimental data within ±0.005 mho cm−1 for the concentration ranges and temperatures studied.
The structure of pentafluorosulfur hypofluorite (SF6OF) has been investigated by electron diffraction from the gas. The results support the proposed hypofluorite structure and indicate that the molecule has octahedrally coordinated sulfur with the O-F bond in staggered configuration. The average S-F distance is 1.53 Á. and the O-F and S-0 distances appear to be about 1.43 and 1.64 Á., in the normal range. The best agreement was obtained from models with oxygen bond angles near the tetrahedral value, F-S-F bond angles very close to 90°, and the opposed S-F and S-O bonds non-colinear by a few degrees.
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