Abundances of light elements in dwarf stars of different ages are important constraints for stellar yields, Galactic chemical evolution and exoplanet chemical composition studies. We have measured C and N abundances and 12C/13C ratios for a sample of 63 solar twins spanning a wide range in age, based on spectral synthesis of a comprehensive list of CH A-X and CN B-X features using HARPS spectra. The analysis of 55 thin disc solar twins confirms the dependences of [C/Fe] and [N/Fe] on [Fe/H]. [N/Fe] is investigated as a function of [Fe/H] and age for the first time for these stars. Our derived correlation [C/Fe]-age agrees with works for solar-type stars and solar twins, but the [N/Fe]-age correlation does not. The relations [C,N/Fe]-[Fe/H] and [C,N/Fe]-age for the solar twins lay under-solar. 12C/13C is found correlated with [Fe/H] and seems to have decreased along the evolution of the local thin disc. Predictions from chemical evolution models for the solar vicinity corroborate the relations [C,N/Fe]-[Fe/H], 12C/13C-age and [N/O]-[O/H], but do not for the 12C/13C-[Fe/H] and [C/O]-[O/H] relations. The N/O ratio in the Sun is placed at the high end of the homogeneous distribution of solar twins, which suggests uniformity in the N-O budget for the formation of icy planetesimals, watery super-earths and giant planets. C and N had different nucleosynthetic origins along the thin disc evolution, as shown by the relations of [C/N], [C/O] and [N/O] against [O/H] and age. [C/N] and [C/O] are particularly observed increasing in time for solar twins younger than the Sun.
We have investigated the thorium (Th) abundance in a sample of 53 thin disc solar twins covering a wide range of ages. These data provide constrains on the mantle energy budget of terrestrial planets that can be formed over the evolution of the Galaxy's thin disc. We have estimated Th abundances with an average precision of 0.025 dex (in both [Th/H] and [Th/Fe]) through comprehensive spectral synthesis of a Th II line present at 4019.1290Å, using very high resolution (R = 115,000) high quality HARPS spectra obtained at the ESO La Silla Observatory. We have confirmed that there is a large energy budget from Th decay for maintaining mantle convection inside potential rocky planets around solar twins, from the Galactic thin disc formation until now, because the pristine [Th/H] ZAMS is super-solar on average under a uniform dispersion of 0.056 dex (varying from +0.037 up to +0.138 dex based on linear fits against isochrone stellar age). Comparing to neodymium (Nd) and europium (Eu), two others neutron-capture elements, the stellar pristine abundance of Th follows Eu along the Galactic thin disc evolution, but it does not follow Nd, probably because neodymium has a significant contribution from the s-process (about 60 per cent).
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