In the organic/inorganic salt hydrate, 6C7H9ClN+·P6O18 6−·2H2O, the cyclo­hexa­phosphate anion resides on an inversion centre. The asymmetric unit consists of three cations, one half-anion and a water mol­ecule. In the crystal, the water mol­ecules and the [P6O18]6− anions are linked by O—H⋯O hydrogen bonds, generating infinite layers parallel to the ab plane. These layers are inter­connected by the organic cations through N—H⋯O hydrogen bonds.

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