A polylactide (PLA type LA 0200 K) was spun in high-speed melt spinning and spin drawing processes. The fibers were characterized with regard to the degree of crystallinity, the orientation, and the textile physical properties. The polymer was produced by a reactive extrusion polymerization process, and its hydrolytic degradation during the processes of drying and spinning and its thermal and rheological properties were characterized.
In this work, melt-spun polypropylene (PP) fibers were treated in an electric field of a corona discharge. The fibers were then characterized using the thermally stimulated current (TSC) spectroscopy. It has been shown that the electret state of corona-treated PP fibers is a result of the combination of Maxwell -Wagner polarization and charge trapping. Activation energies and relaxation times for these processes have been determined, and characteristics of trapping sites have been calculated. The electret state induced in PP fibers by the corona discharge treatment holds for a long time (several months). Our analysis of the effect of processing temperature and electric field intensity on the characteristics of the electret state in melt-spun PP fibers allows one to specify optimum technological regimes for industrial production of PP-based electret filter materials.
Melt spinning of polymer melts is a formation process makingextremely high demands on the material's continuous deformation ability by highest deformation speeds. The structural conditions of a thermoplastic polymer which are necessary for spinnability have not been exactly cleared up yet. But this knowledge gap must be closed especially with regard to the many efforts to spin fibers with new properties made from modified polymers or polymer blends. The article is begun with a pragmatic definition of the spinnability of a polymer melt. The discussion of a structural rheological model shows a correlation between dynamic rheological measurement datas of polymer melts and experimental experience about their spinnability. Proceeding from a comprehensive description of possible failure cases (fiber beak problems), results of rheological measurement of a number of different polymers, which are spinnable well, not as well or not at all, are compared. The article is concluded by some comments on open problems which have to be solved by basic research in the near future.
Online measurements of the temperature and the diameter of fibers in the melt spinning process of thermoplastics are discussed. The temperature and the diameter of fibers can be applied in many fields such as fiber formation modelling, cooling rate behavior (Nusselt number), and rheological investigations (apparent extensional viscosity) of polymers. The online measurements along the spinline were carried out with an infrared camera during the melt spinning process. Two different experiments were designed and carried out to find the correction factor, i.e., the emissivity. The results show that the emissivity correction factor depends on the polymer type and the fiber diameter. Usually the diameter of the fibers is measured by an instrument or by direct velocity measurements invoking the continuity equation. In this new approach the diameter is found directly by the evaluation of the measured temperature. Therefore only one apparatus, namely an infrared camera taking snapshots, is required to find the fiber diameter. The key of this method can be seen in the temperature difference between the fiber and the environment. A mathematical
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