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A series of rhenium(I) dinitrogen complexes were prepared containing predominantly amine ligands. On the basis of infrared and electrochemical data, a system was selected that was anticipated to be a suitable precursor for an elongated dihydrogen complex. Upon oxidation by AgOTf, the dinitrogen ligand of fac-[Re(PPh(3))(PF(3))(dien)(N(2))](+) (3) is replaced with triflate to generate 13, fac-[Re(PPh(3))(PF(3))(dien)(OTf)]OTf, a convenient precursor to rhenium(II) and rhenium(I) amine complexes. Reduction of the rhenium(II) triflate 13 under 1 atm of hydrogen gas generates the complex fac-[Re(dien)(PPh(3))(PF(3))(dien)(H(2))](+) (fac-14). T(1) measurements indicate a dihydrogen species with a H-H distance of 1.38 +/- 0.03 Å. The HD analog displays a J(HD) of 6.7 Hz, corresponding to a H-H distance of 1.31 +/- 0.03 Å, a value in good agreement with that determined from T(1) data and among the largest ever measured for an elongated dihydrogen system.