Electrical and thermal transport properties of liquid Fe under high pressure have important implications for the dynamics and thermal evolution of planetary cores and the geodynamo. However, electrical resistivity (ρ) and thermal conductivity (k) of liquid Fe at high pressure still remain contentious properties. To date, only two experimental investigations of ρ of liquid Fe in the pressure region below 7 GPa are reported in literature. Here we report the results of measurements of ρ for solid and liquid Fe (inversely proportional to k through the Wiedemann-Franz law) at pressures from 3 to 12 GPa, using a large multi-anvil press. We show that ρ of liquid Fe decreases as a function of pressure up to the δ-γ-liquid triple point at ~5.2 GPa, and subsequently remains invariant from 6 to 12 GPa, which is consistent with an earlier study on liquid Ni. Our results demonstrate an important effect of solid phase on the structure and properties of liquid Fe. Our values of ρ for solid and liquid Fe are used to calculate k in Mercury’s solid inner core and along the adiabat in the liquid outer cores of Moon, Ganymede, Mercury and Mars. Our robust values of thermal conductivity place the focus on uncertainties in thermal expansion as the cause of variation in values of core conducted heat. Except for Mercury, our adiabatic heat flux values in these terrestrial cores validate the use of similar values used in several previous studies. Our high values of core adiabatic heat flux in Mercury would provide a stabilizing effect on, and lead to an increase in thickness of, the thermally stratified layer at the top of the core.
Studies of meteor trails have until now been limited to relatively simple models, with the trail often being treated as a conducting cylinder, and the head (if considered at all) treated as a ball of ionized gas. In this article, we bring the experience gleaned in other fields to the domain of meteor studies, and adapt this prior knowledge to give a much clearer view of the microscale physics and chemistry involved in meteortrail formation, with particular emphasis on the first 100 or so milliseconds of the trail formation. We discuss and examine the combined physico-chemical effects of meteor-generated and ablationally amplified cylindrical shock waves which appear in the ambient atmosphere immediately surrounding the meteor train, as well as the associated hyperthermal chemistry on the boundaries of the high temperature postadiabatically expanding meteor train. We demonstrate that the cylindrical shock waves produced by overdense meteors are sufficiently strong to dissociate molecules in the ambient atmosphere when it is heated to temperatures in the vicinity of 6,000 K, which substantially alters the considerations of the chemical processes in and around the meteor train. We demonstrate that some ambient O 2 , along with O 2 that comes from the shock dissociation of O 3 , survives the passage of the cylindrical shock wave, and these constituents react thermally with meteor metal ions, thereby subsequently removing electrons from the overdense meteor train boundary through fast, temperature independent, dissociative recombination governed by the second Damköhler number. Possible implications for trail diffusion and lifetimes are discussed.
Characterization of transport properties of liquid Ni at high pressures has important geophysical implications for terrestrial planetary interiors, because Ni is a close electronic analogue of Fe and it is also integral to Earth's core. We report measurements of the electrical resistivity of solid and liquid Ni at pressures 3–9 GPa using a 3000 t multianvil large volume press. A four‐wire method, in conjunction with a rapid acquisition meter and polarity switch, was used to overcome experimental challenges such as melt containment and maintaining sample geometry and to mitigate the extreme reactivity/solubility of liquid Ni with most thermocouple and electrode materials. Thermal conductivity is calculated using the Wiedemann‐Franz law. Electrical resistivity of solid Ni exhibits the expected P dependence and is consistent with earlier experimental values. Within experimental uncertainties, our results indicate that resistivity of liquid Ni remains invariant along the P‐dependent melting boundary, which is in disagreement with earlier prediction for liquid transition metals. The potential reasons for such behavior are examined qualitatively through the impact of P‐independent local short‐range ordering on electron mean free path and the possibility of constant Fermi surface at the onset of Ni melting. Correlation among metals obeying the Kadowaki‐Woods ratio and the group of late transition metals with unfilled d‐electron band displaying anomalously shallow melting curves suggests that on the melting boundary, Fe may exhibit the same resistivity behavior as Ni. This could have important implications for the heat flow in the Earth's core.
The electrical resistivity and thermal conductivity of liquid Fe alloys are the least constrained parameters in Earth's outer core (OC). These parameters are important as they modulate energy budget available for the geodynamo and affect the spatiotemporal evolution of the core. We report results of electrical resistivity measurements on solid and liquid Fe‐4.5 wt%Si from 3–9 GPa using a large volume multianvil press. The internally modified 18/11 octahedron cell was used to maintain the geometry of the liquid sample and to delay the onset of contamination. Electrical resistivity of solid Fe‐4.5Si decreases steadily with pressure and is very sensitive to increasing temperature‐driven onset of phase transitions. Along the melting boundary and within error, electrical resistivity remains constant and assumes the same value of 120 μΩcm as observed in pure liquid Fe. The results are interpreted in the context of icosahedral short‐range order (ISRO) structures that exhibit higher concentration with increasing pressure. Along the melting line, the increasing concentration of ISROs reduces charge carrier mean free path and prevents decrease of electrical resistivity with increasing pressure as seen in liquid metals, Cu, Ag, and Au, which do not have ISROs. In light of recent developments in understanding of the structure and dynamics of liquid transition metals and alloys, we postulate that our findings are applicable to other Fe alloys in the OC with small light element (C, S, and O) content. We calculated an adiabatic heat flow of 9.4–12 TW at the OC‐CMB interface, which admits thermal convection.
Convection of the liquid iron (Fe) outer core and electrical properties of Fe are responsible for the geodynamo that generates the geomagnetic field. Recent results showed the thermal conductivity of the core and related conductive heat flux may be much larger than previously accepted, suggesting that thermal convection would not be an energy source to power the geodynamo. Here we report experimental measurements of the electrical resistivity of solid and liquid Fe which show invariant values along the melting boundary at pressures up to 24 GPa. The observed resistivity invariance was extrapolated to Earth's predominantly Fe solid inner core and liquid outer core conditions and, using the Wiedemann‐Franz law, the thermal conductivity was calculated. We calculate a conductive core heat flow of 8–9 TW at the core‐mantle boundary. These results provide strong support for thermal convection as a geodynamo energy source.
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