High power microwave discharges in S2 vapour at pressures of several bars have been discovered as a highly eficient white light source several years ago [l]. The discharge spectrum is originating mainly from bound-bound transitions in the S2 B 3Cu--X 3Cg-band system. At such high S2 pressures re-absorption is an essential mechanism shifting the spectral maximum from the UV into the visible region [ 2 ] .Assuming spherical symmetry, local thermal equilibrium and a cubic temperature profile the onedimensional radiation transport equation is solved for each of the 330 vibronic bands connecting the niveaus v' = 0...9 and v" = 0...32 yielding a quantitative description of the spectrum with only two free parameters: the maximum discharge temperature T,, and the mean width 8vvib of a vibronic band. The response of the spectrum to variations of experimental conditions (Sz pressure, input power, ... ) may be expressed by very reasonable changes of these model parameters: The input power determines the total amount of radiation (via the value of Tmm) and the S2 pressure influences the position of the spectral maximum (reflected by the value of 8vyib). In the red and IR the experimental spectrum is higher than the simulation indicating contributions of continuum radiation or other molecular transitions which are not included in the model.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.