A series of experiments has been conducted in a low-speed wind tunnel in which measurements were performed in a two-dimensional turbulent shear layer experiencing the mixing of both a passive and a chemically reacting species. The low-temperature air in the jet's primary flow was seeded with dilute concentrations of N2O4so that the dissociation reaction N2+ N2O4[harr ] 2NO2+ N2occurred in a near-equilibrium manner within the mixing layer owing to the turbulent mixing properties and the imposed temperature gradient. Mean and fluctuating values of velocity, temperature and NO2concentration were measured up to axial distances of 25 in. for jet velocities of 23 and 50ft/s (Rex[les ] 7 × 105) and for three primary temperatures (252, 273 and 305°K). Velocity and temperature measurements were performed with hot-wire probes, whereas a fibre optics light sensor probe was used to measure NO2concentrations. Local correlations between species and other fluid properties were obtained by positioning a hot-wire sensor within the light gap of the fibre optics probe and simultaneously recording output signals from both probes. A relatively complete set of turbulent statistics was measured for the non-reacting shear layer, including such results as temperature/species correlations, probability densities, filtered and unfiltered moving-frame velocities, skewness and flatness factors, spectra, velocity and temperature integral scales, intermittency factors for velocity, temperature and passive species, and conventional intensities. Some typical results from the investigation are as follows: the turbulent Schmidt and Lewis numbers were 0·5 and 1·0 respectively; the correlation between passive NO2concentration and temperature was approximately 0·95; dramatic changes consistent with equilibrium chemistry occurred in NO2concentration profiles with chemical reaction; velocity, temperature and concentration spectra were comparable over a 2½-decade range in wavenumber (k−2); spectra, probability densities, time-trace data and smoke-seeded shear-layer photographs indicate that, for axial locationsx=x0[ges ] 18·5 in. and for speedsu1[ges ] 23ft/s, undisturbed edge fluid rarely penetrates completely across the mixing region. Although not specifically addressed during the current study, measured results herein suggest that the turbulent motion for the present shear layer is characterized more by random and/or three-dimensionality effects than by large-scale two-dimensional coherent structures, as has been observed recently in other shear-layer investigations.
Nitrate reductase from wheat (Tititum aestivum L. cv Bindawarra) leaves is inactivated by pretreatment with NADH, in the absence of nitrate, a 50% loss of activity occurring in 30 minutes at 25C with 10 micromolar NADH. Nitrate (50 micromolar) prevented inactivation by 10 micromolar NADH while cyanide (1 micromolar) markedly enhanced the degree of inactivation.A rapid reactivation of NADH-inactivated nitrate reductase occurred after treatment with 0.3 mlllimolar ferricyanide or exposure to light (230 milliwatts per square centimeter) plus 20 micromolar flavin adenine dinucleotide. When excess NADH was removed, the enzyme was also reactivated by autoxidation. Nitrate did not influence the rate of reactivation.Leaf nitrate reductase, from plants grown for 12 days on 1 milolar nitrate, Isolated in the late photoperiod or dark period, was activated by ferricyanide or light treatment. This suggests that, at these times of the day, the nitrate reductase in the leaves of the low nitrate plants is in a partially inactive state (NADH-inactivated). The nitrate reductase from moisture-stressed plants showed a greater degree of activation after light treatment, and inactive enzyme in them was detected earlier in the photoperiod.
Nettelbeck & Rabbitt (1992) found that measures of speed of performance with low knowledge requirements (four-choice reaction time, inspection time and coding-substitution) accounted substantially for age-related changes among 104 persons aged from 54 to 85 years in a number of more complex cognitive measures reflecting general fluid ability. However, the numbers of words recalled from a list after either a single brief viewing of each word, or following a cumulative learning procedure across four trials, provided an exception to this general trend, leading to the conclusion that some aspects of memory may be independent of mental speed. A follow-up of 82 of the same people 18-20 months later was designed to partition performance in a similar cumulative learning procedure into an initial first recall component and a subsequent learning component. This was accomplished by fitting individual cumulative learning data with a hyperbolic power function which met the theoretical requirement of defining separate initial recall and learning parameters. These parameters were found to be independent and it was concluded that learning involved rehearsal, whereas first recall did not. The hyperbolic power function provided a good account for 92 per cent of individual cases. Analyses which combined Nettelbeck & Rabbitt's (1992) data with new measures confirmed the reliability of these authors' results. Furthermore, it was found that first recall, but not learning, was mediated by processing speed. Learning was relatively unaffected by age-related slowing in mental speed, suggesting that Nettelbeck & Rabbitt's results were the consequence of a strong rehearsal component in their memory tasks. Thus, while mental slowing is clearly one important aspect of cognitive decline during old age, it does not constitute a sufficient explanation for changes in all areas of cognitive functioning. Specifically, age-decline in rate of learning with rehearsal appeared to be independent of slowing in speed of information processing.
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