We utilize real-time scattering techniques to examine the mesoscopic and molecular response of a nonionic surfactant hexagonal mesophase to shear and extensional flows. These results are correlated with the rheological response in simple shear. During shear there is an initial modest orientation of the surfactant rods along the flow direction. This is followed by a progressive further increase in alignment over the next 500 shear units. This process of rod alignment corresponds to the progressive development of shear thinning, which might be anticipated from molecular theories developed for liquid crystalline polymer systems (LCPs). It is surprising, however, that equilibrium requires such large strains, not seen in LCPs, possibly due to a unique feature of the surfactant mesophase: the ability to rupture under stress and reform. This long structure induction time has clear implications for conventional rheology, which may rarely reach an equilibrium response. By contrast, in an extensional flow the orientation is achieved much faster, over about two strain units, and is much more perfect (P 2 ∼ 0.9). Threads spun are stable, which may point to extensional thickening. It is likely that in real flows, relevant to industrial applications, it is the response to extensional components of the flow (such as convergent channels, flow around obstacles, bifurcations) which dominates the behavior of the mesophase.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2025 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.