Abstract. Some possible physical processes are analysed that cause, under the condition of additional ionisation in a pre-breakdown electric field, emissions in the infrared (IR) interval. The atmospheric transparency region of the IR spectrum at wavelengths of 7-15 µm is taken into account. This transparency region corresponds to spectral lines of small atmospheric constituents like CH 4 , CO 2 , N 2 O, NO 2 , NO, and O 3 . The possible intensities of the IR emissions observable in laboratories and in nature are estimated. The acceleration process of the electrons in the pre-breakdown electrical field before its adhesion to the molecules is analyzed. For daytime conditions, modifications of the adsorption spectra of the scattered solar emissions are studied; for nighttime, variations of emission spectra may be used for the analysis.