:The densities (ρ) and ultrasonic velocities (C) of binary mixture of diisopropyl ether (DIPE) and bromobenzene (BB) have been measured at different frequencies (1 MHz, 3 MHz and 5 MHz) over the entire range of mole fraction of diisopropyl ether (DIPE) at temperature 303 K. The intermolecular free length (L f ), isentropic compressibility (β), acoustic impedance (Z) and excess values of isentropic compressibility (β E ) and acoustic impedance (Z E ) have been computed using values of ultrasonic velocity (C) and density (ρ).The ultrasonic velocity, intermolecular free length are positive whereas the excess values of isentropic compressibility and acoustic impedance are negative over the entire composition range of DIPE which indicates presence of specific interactions between unlike molecules. The results are discussed in the light of intermolecular interactions occurring in the mixtures.
This paper reports experimental and theoretical investigations on plasma turbulence in the source plasma of a Large Volume Plasma Device. It is shown that a highly asymmetrical localized thin rectangular slab of strong plasma turbulence is excited by loss cone instability. The position of the slab coincides with the injection line of the primary ionizing energetic electrons. Outside the slab, in the core, the turbulence is weaker by a factor of 30. The plasma turbulence consists of oblique [θ=tan−1(k⊥/k||)≈87°] Quasi-Longitudinal (QL) electromagnetic whistlers in a broad band of 40kHz<f≤80 kHz with k⊥∼1.2 cm−1 and k||∼0.06cm−1. Experimental observations suggest that the primary agent for the turbulence is not driven by primary ionizing energetic electrons but by the loss cone feature in the velocity distribution of reflected energetic electrons. A magnetic mirror is formed in the Electron Energy Filter when it is energized. It is shown that it is this mirror which is responsible for both reflection of the energetic electrons and imposing loss cone feature on it. Theoretical framework is based upon Oblique whistler approximation by Sharma and Vlahos [Astrophys. J. 280, 405 (1984)] and Verkhoglyadova et al. [J. Geophys. Res. 115, A00F19 (2010)] and Quasi Longitudinal (QL) whistlers by Booker and Dyce [Radio Sci. J. Res 69D (1965)] for excitation of the plasma turbulence in the magnetosphere.
The densities ( ) and ultrasonic velocities (C) of binary mixtures of a polar liquid like acetone and toluene have been measured at different frequencies (lMHz, 3MHz and 5MHz) over the entire range of mole fraction of acetone at temperature 303.16k. The intermolecular free length (L f ), isentropic compressibility ( ), acoustic impedance (Z), excess values of isentropic compressibility ( ) and acoustic impedance (Z E ) have been computed using values of ultrasonic velocity (C) and density ( ). The ultrasonic velocity (C), intermolecular free length (L f ) and excess values of isentropic compressibility are positive whereas excess values of acoustic impedance is negative for the entire composition range which indicates the specific interaction between unlike molecules. The results are discussed in the light of intermolecular interactions occurring in the solutions.
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