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Increased environmental concerns and global warming have diverted effort all over the world to focus on renewable and sustainable resources for the next generation of composite products due to their recyclability, renewability, cost effectiveness, and satisfactory mechanical performance. Bio/natural fibers which are environment friendly materials employed as reinforcement have led to developing a biocomposite for reduction in greenhouse emission and carbon footprints. However, biofibers are also having some limitations that need to be addressed including poor compatibility between the reinforcing fiber matrices, high moisture absorption, swelling, poor chemical and fire resistance, and high dispersion of mechanical properties. A lot of research has been performed on physical and mechanical properties of natural fiber composite. Properties of such novel composite mainly depend on adhesion between fiber and matrices. Consequently, poor adhesion, high moisture absorption, and swelling lead to formation of crack in both the matrix and fiber. Therefore, numerous techniques have been tried till date to modify both fiber surfaces to enhance their adhesion and reduce their water absorption. This review article provides comprehensive information about effect of various surface modification techniques that include alkaline, silane, acetylation, permanganate, peroxide, benzoylation, acrylonitrile grafting, maleic anhydride grafted, acrylation, and isocyanate. In addition, the effects of cellulose, hemicellulose, lignin, and pectin of biofibers are also reported. This review concluded that chemical treatment of biofibers with 5% NaOH concentration improves the physical, mechanical, and thermal properties of the resulting composites compared to untreated fiber composites.

The aim of the present work is to develop novel hybrid composites using areca, kenaf, and snake grass fibers as reinforcement and epoxy as the matrix. The areca, kenaf, and snake grass fibers were extracted from Catechu Linnaeus, Hibiscus cannabinus, and Sansevieria Ehrenbergii plants, respectively, and treated with 5% NaOH to improve the interfacial adhesion between the hydrophilic fiber and the hydrophobic matrix. Hybrid composites were developed by the compression molding technique and formulated based on the weight fraction of fibers. Tensile, flexural, and impact strength and hardness samples were prepared as per ASTM D 3039, ASTM D 790, ASTM D 256, and ASTM D 2240, respectively. The effects of alkaline treatment on developed hybrid composites were investigated. The developed hybrid composites with 20% wt. snake grass and 10% wt. areca fiber present interesting mechanical properties with a tensile strength of 58 MPa, flexural strength of 124 MPa, impact strength of 5.24 kJ/m2, and hardness of 88. The results indicate that maximum mechanical properties were obtained for alkaline-treated fiber composites with 20% wt. snake grass fiber compared to untreated fiber composites owing to better adhesion between the treated fiber and the matrix. The effect of alkaline treatment was analyzed by Fourier transform infrared. The fractured surfaces of tested samples were analyzed by scanning electron microscopy.

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This paper is focused on developing composites using kenaf fibers, epoxy polymer, and incorporation of graphene fillers. The kenaf fibers are treated with 5% NaOH to remove the hydrophilic nature and reinforced it with the hydrophobic matrix. The composites are fabricated using the compression moulding technique by keeping 60 wt.% epoxy as constant, and the graphene and kenaf fiber weights are changed accordingly. The samples for tensile, flexural, impact, hardness, and water absorption tests are prepared as per the ASTM D3039, D790, D256, D2240, and D572 standards, respectively. The effect of graphene fillers in the 5% NaOH-treated kenaf fibers reinforced with the epoxy matrix is tested. Among the various samples, sample 4 which has 6% graphene addition in the epoxy matrix reinforced with 5% treated kenaf fiber displayed the highest tensile strength of 63 MPa, flexural strength of 97 MPa, impact strength of 9.56 kJ/m2, hardness value of 97, and lower water absorption of 5.13%. This is due to the proper dispersion of graphene fillers in the matrix which caused better interfacial adhesion between the fiber and matrix. The water absorption test showed the lowest value in sample S5 as the graphene fillers obstruct water penetration in the fibers. SEM analysis is done on the prepared samples to study the surface flaws and structural changes.