[1] The borehole Yaxcopoil-1, drilled within the Chicxulub meteoritic impact structure (Mexico), was completely cored from 404 to 1511 m through postimpact Tertiary limestones underlain by impactites. The impactites comprise impact melt-rich, suevitic breccia followed by megablocks of Cretaceous limestones, calcarenites, dolomites, and anhydrites. Measurements of porosity, density, and thermal parameters on 450 samples (equidistant sampling, complete depth range) and of ultrasonic velocities and electric resistivity on 80 representative samples are used to investigate the physical properties of carbonate rocks and to study the influence of the impact. Experiments under elevated pressure, calculations using frequency-dependent Biot-Gassmann theory, and crosschecking with borehole logs, where available, show that ultrasonic laboratory and sonic in situ data correspond. Sonic and electric quasi-continuous logs are obtained from empirical correlations with thermal conductivity, density, and porosity and consideration of mineralogical composition and microstructure. These data give constraints on interpretation and geophysical modeling of, e.g., seismic and gravity data. In the Tertiary postimpact limestone section, the rock fabric (porosity) influences the physical properties. The upper boundary of the impactites is distinctly determined by the high inhomogeneity factor and anisotropy coefficient of thermal conductivity and by the temperature gradient from high-resolution borehole temperature measurements. All physical properties indicate that the upper part of the suevitic breccia can be distinguished from the lower suevite unit. In the Cretaceous megablocks, a high variability of all properties (particularly, thermal conductivity, density of solid material, and temperature gradient) due to the high variability in the mineral composition (calcite, dolomite, anhydrite) is observed.
A new non-contact and non-destructive optical scanning instrument provided a large number of high-precision measurements of thermal conductivity tensor components in samples of sedimentary and impact rocks, as well as new insights into interrelations between thermal conductivity and other physical properties. More than 800 core samples (dry and fluid-saturated) of sedimentary rocks from different Russian oil-gas deposits and impact rocks from the well ''No¨rdlingen 1973'' drilled in the Ries impact structure (Germany) were studied using optical scanning technology. It was established that the thermal conductivity parallel to the stratification is more informative for petrophysical investigations than the thermal conductivity perpendicular to the layering. Different approaches were developed to estimate porosity, permeability, pore space geometry, and matrix thermal conductivity with a combination of thermal conductivity measurements in dry and fluid-saturated samples and mathematical modelling. These approaches allow prediction of the rock porosity and permeability and their spatial distribution along a well using thermal conductivity measurements performed with the optical scanning instrument directly applied to cores. Conditions and constraints for using Lichtenecker-Asaad's theoretical model for the estimation of porosity and thermal conductivity of sedimentary rocks were determined. A correlation between thermal conductivity and acoustic velocity, porosity, density, and electric resistivity of impact rocks was found for different rock types. New relationships between permeability, electrical and thermal conductivity found for sedimentary rocks are described.
Abstract-Physical properties were determined in a first step on post-impact tertiary limestones from the depth interval of 404-666 m of the Yaxcopoil-1 (Yax-1) scientific well, drilled in the Chicxulub impact crater (Mexico). Thermal conductivity, thermal diffusivity, density, and porosity were measured on 120 dry and water-saturated rocks with a core sampling interval of 2-2.5 m. Nondestructive, non-contact optical scanning technology was used for thermal property measurements including thermal anisotropy and inhomogeneity. Supplementary petrophysical properties (acoustic velocities, formation resisitivity factor, internal surface, and hydraulic permeability) were determined on a selected subgroup of representative samples to derive correlations with the densely measured parameters, establishing estimated depth logs to provide calibration values for the interpretation of geophysical data. Significant short-and long-scale variations of porosity (1-37%) turned out to be the dominant factor influencing thermal, acoustic, and hydraulic properties of this post impact limestone formation. Correspondingly, large variations of thermal conductivity, thermal diffusivity, acoustic velocities, and hydraulic permeability were found. These variations of physical properties allow us to subdivide the formation into several zones. A combination of experimental data on thermal conductivity for dry and water-saturated rocks and a theoretical model of effective thermal conductivity for heterogeneous media have been used to calculate thermal conductivity of mineral skeleton and pore aspect ratio for every core under study. The results on thermal parameters are the necessary basis for the determination of heat flow density, demonstrating the necessity of dense sampling in the case of inhomogeneous rock formations.
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