This work concerns the state of the art for use of impedance spectroscopy for studying the evolving microstructure of cement-based materials during hydration. Features of the spectra are discussed and related to components of the microstructure with the assistance of pixel-based computer modeling techniques. It is proposed that the enormously high relative dielectric constants (-10') observed just after set are the result of dielectric amplification and are related to the distribution of pore sizes and the thickness of product C-S-H layers separating the pores. The conductivity is related to the volume fraction of porosity, the conductivity of the pore solution, and the interconnectivity of the porosity. The conductivity, when normalized by that of the pore solution, i.e., inverse formation factor, is a measure of this interconnectivity and can be used to predict such engineering properties as ionic diffusivity and water permeability. Composite mixing laws are employed to aid in explaining the behavior of the conductivity and to obtain a qualitative measure of the pore shape with hydration. Procedures for predicting the conductivity of the pore solution and for subtracting out electrode lead effects a t high frequency are discussed.

A model of the local microstructure of a bundle of fibers is simulated and used as the basis for calculations of transport properties. This, in turn, can be used in a macroscopic model of the chemical vapor infiltration process. An expanding/overlapping circle representation of the microstructure simulates the deposition of matrix in a uniaxial bundle of fibers. An iterative heat conduction algorithm is used to calculate the transverse thermal conductivity based on the thermal conductivities of the solid and gas phases. The permeability of gas through the microstructure is calculated for flow both parallel and transverse to overlapping cylinders using a Stokes equation and assuming a Darcy's law behavior. Both the simulations of the microstructure and associated calculations of the transport properties compare favorably with experimental data. Darcy's law for the behavior of gas in a bundle of fibers is shown to be valid for gas pressures of 5-13 kPa.