This work describes a successful approach toward the development of a carbon fiber-reinforced composite based on an optimized nanofilled resin for industrial applications. The epoxy matrix is prepared by mixing a tetrafunctional epoxy precursor with a reactive diluent which allows reduction of the viscosity of the epoxy precursor and facilitation of the dispersion of 0.5% wt multiwall carbon nanotubes. The proper choice of the viscosity value and the infusion technique allow improvement of the electrical properties of the panels. The obtained in-plane electrical conductivity is about 20 kS m-1, whereas a value of 3.9 S m-1 is achieved for the out of plane value. Such results confirm that the fibers govern the conduction mechanisms in the direction parallel to the fibers, whereas the percolating path created by the effective distribution of carbon nanotubes achieved by resin formulation and adopted processing approach lead to a significant enhancement of the overall electrical performance of the composites
The purpose of this paper is to describe the first experiments to manufacture self-healing carbon fiber reinforced panels (CFRPs) for the realization of structural aeronautic components in order to address their vulnerability to impact damage in the real service conditions.In this paper, autonomically healing CFRPs with damage resistance and self-healing function are proposed. In the development of self-healing aeronautic materials it is critical that self-healing activity functions in adverse weather conditions and at low working temperatures which can reach values as low as -50°C
A suitably modified resin film infusion (RFI) process was used for manufacturing carbon fiber-reinforced composites (CFRCs) impregnated with a resin containing nanocages of glycidyl polyhedral oligomeric silsesquioxane (GPOSS) for enhancing flame resistance and multi-wall carbon nanotubes (MWCNTs) to contrast the electrical insulating properties of the epoxy resin. The effects of the different numbers (7, 14 and 24) of the plies on the equivalent direct current (DC) and alternating current (AC) electrical conductivity were evaluated. All the manufactured panels manifest very high values in electrical conductivity. Besides, for the first time, CFRC strings were analyzed by tunneling atomic force microscopy (TUNA) technique. The electrical current maps highlight electrically conductive three-dimensional networks incorporated in the resin through the plies of the panels. The highest equivalent bulk conductivity is shown by the seven-ply panel characterized by the parallel (σ//0°) in-plane conductivity of 16.19 kS/m. Electrical tests also evidence that the presence of GPOSS preserves the AC electrical stability of the panels.
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