(Received ?; revised ?; accepted ?. -To be entered by editorial office)Despite its fundamental and practical relevance, flow structure and evolution within volatile mixture drops remains largely unexplored. We study experimentally, using particle image velocimetry (PIV), the evolution of internal flow during the evaporation of ethanol-water mixture drops for different initial concentrations. The investigation revealed the existence of three stages in the evolving flow behaviour within these binary volatile drops. We propose an analysis of the nature of the flow and focus on understanding successive flow stages as well as transition from multiple vortices to a monotonous outward flow. We show that the existence of multiple vortices during the first stage is driven by local concentration gradients along the interface. When the more volatile component (in this case ethanol) is depleted, the intensity of this M arangoni flow abruptly declines. Towards the end of the first stage, ethanol is driven from the bulk of the drop to the interface to sustain weakening concentration gradients. Once these gradients are too weak, the solutal M arangoni number becomes sub-critical and the driving force for the flow switches off. The evolution of flow structure and transition between stages is found to be well correlated with the ratio of Marangoni and Reynolds numbers. Furthermore, we argue that whilst the observed vortices are driven by surface tension shear stress originating at the liquid/vapour interface, the transition in flow and its dynamics is entirely determined by viscous dissipation. The comparison between the analytical expression for vorticity decay based on viscous dissipation and the experimental data show a very good agreement. The analysis also shows that regardless of the initial concentration, for same size drops, the transition in flow follows exactly the same trend. This further supports the hypothesis of a viscous dissipation transition of the flow. The last stage is satisfactorily explained based on non-uniform evaporation and continuity driven flow.

We propose a general theoretical expression for sessile droplets' evaporation, incorporating thermal effects related to the thermal resistance of the substrate and liquid properties. We develop an expression which accounts for thermal effects associated with evaporative cooling; the latter leads to a reduction in the rate of evaporation, which is not accounted for in the current theories, i.e. ‘isothermal diffusion theories’. The threshold for transition to a regime in which thermal effects start to be significant is identified through a dimensionless number which includes substrate and liquid properties as well as the kinetics of evaporation. The proposed theory is validated against experimental data in a very wide range of conditions and for a variety of systems. The developed expression extends the domain of use of diffusion-based models for droplet evaporation and accurately describes some aspects of the phenomenon which, to the best of our knowledge, are highlighted for the first time.

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