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Oleic, linoleic, and linolenic acids are the main components of canola oil and their physiochemical properties decide on the use of canola oil as fuel for diesel engines. Therefore, the measurements of the surface tension of oleic, linoleic, and linolenic acids being the components of the canola oil, as well as their contact angles on the polytetrafluoroethylene (PTFE), poly(methyl methacrylate) (PMMA), and engine valve, were made. Additionally, the surface tension and contact angle on PTFE, PMMA, and the engine valve of the oleic acid and n-hexane mixtures were measured. On the basis of the obtained results, the components and parameters of oleic, linoleic, and linolenic acids’ surface tension were determined and compared to those of the canola oil. Next, applying the components and parameters of these acids, their adhesion work to PTFE, PMMA, and the engine valve was calculated by means of various methods.

The article discusses the problem of using canola oil and n-hexane mixtures in diesel engines with storage tank fuel injection systems (common rail). The tests results of the combustion process in the dynamic operating conditions of an engine powered by these mixtures are presented. On the basis of the conducted considerations, it was found that the addition of n-hexane to canola oil does not change its energy properties and significantly improves physicochemical properties such as the surface tension and viscosity. It contributes to the improvement of the flammable mixture preparation process and influences the course of the combustion process.

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