Rahima Dilshad scite author profile

Orange‐yellow plate‐like crystals of the title compound were obtained from the reaction of [Me4N]2WO2S2 or [Me4N]2WOS3 with CuCl and [Me4N]Cl in MeCN solution. They are hexagonal, space group P63cm (No.185), with unit cell parameters a = 11.638(4) Å, c = 17.970(7) Å, Z = 2. The crystal structure was determined from single crystal X‐ray diffraction data (MoKα‐radiation) and refined to R = 0.049. The structure is characterized as an alternating packing of cubane‐like [WOS3(CuCl)3Cl]3‐ and Cl‐ anions.

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Rahima Dilshad

Triosmium and triruthenium clusters containing diazaheterocycles

Triosmium and triruthenium clusters containing the 4-methylthiazolide ligand: crystal structures of [Os₃(µ-H)(CO)₁₀(µ-2,3-η²-CNCMeCHS)], [Os₃(µ-H)(CO)₉(µ-2,3-η²-CNCMeCHS)(PPh₃)] and [Os₃(µ-H)(CO)₈(µ-2,3-η²-CNCMeCHS)(PPh₃)₂]

Triruthenium clusters derived from the reactions of [Ru3(CO)12] with benzothiazole, pyrimidine-2-thione and benzimidazole-2-thione; X-ray structures of [Ru3(μ-H)(μ-2,3-η2-NSC7H4)(CO)10] and [Ru3(μ-H)(μ3-η2-SN2C4H3)(CO)9]

Triosmium clusters derived from the reactions of thioureas with dodecacarbonyltriosmium: Crystal structures of [Os3(CO)11{η 1-SC(NMe2)2}], [Os3(CO)9(μ-OH)(μ-OMeOCO){η 1-SC(NMe2)2}] and [(μ-H)Os3(CO)9{μ 3-NHC(S)NH2}]

[Me₄N]₅[WOS₃(CuCl)₃Cl]Cl₂ ‐ a Cluster Compound with Alternating Anion Packing

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Rahima Dilshad

Triosmium and triruthenium clusters containing diazaheterocycles

Triosmium and triruthenium clusters containing the 4-methylthiazolide ligand: crystal structures of [Os3(µ-H)(CO)10(µ-2,3-η2-CNCMeCHS)], [Os3(µ-H)(CO)9(µ-2,3-η2-CNCMeCHS)(PPh3)] and [Os3(µ-H)(CO)8(µ-2,3-η2-CNCMeCHS)(PPh3)2]

Triruthenium clusters derived from the reactions of [Ru3(CO)12] with benzothiazole, pyrimidine-2-thione and benzimidazole-2-thione; X-ray structures of [Ru3(μ-H)(μ-2,3-η2-NSC7H4)(CO)10] and [Ru3(μ-H)(μ3-η2-SN2C4H3)(CO)9]

Triosmium clusters derived from the reactions of thioureas with dodecacarbonyltriosmium: Crystal structures of [Os3(CO)11{η 1-SC(NMe2)2}], [Os3(CO)9(μ-OH)(μ-OMeOCO){η 1-SC(NMe2)2}] and [(μ-H)Os3(CO)9{μ 3-NHC(S)NH2}]

[Me4N]5[WOS3(CuCl)3Cl]Cl2 ‐ a Cluster Compound with Alternating Anion Packing

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Triosmium and triruthenium clusters containing the 4-methylthiazolide ligand: crystal structures of [Os₃(µ-H)(CO)₁₀(µ-2,3-η²-CNCMeCHS)], [Os₃(µ-H)(CO)₉(µ-2,3-η²-CNCMeCHS)(PPh₃)] and [Os₃(µ-H)(CO)₈(µ-2,3-η²-CNCMeCHS)(PPh₃)₂]

[Me₄N]₅[WOS₃(CuCl)₃Cl]Cl₂ ‐ a Cluster Compound with Alternating Anion Packing