Despite a large number of existing studies about direct
carbon
fuel cells (DCFCs), sufficient power generation has remained a major
technical challenge for the commercialization of DCFCs. This study
was designed to implement the benefits of a carbon-filled porous anode
developed in our recent studies in a unit cell. First, we developed
a new tubular cell assembly comprising an anode, a thin matrix, and
a tubular cathode with a certain number of holes in its surface. By
employing a reference electrode, we measured the resistance and
I
–
V
–
P
characteristics
of the anode, a cathode with a single hole, and the entire cell. As
a result, we found that the cathode performance was degraded by resistance
to ionic mass transfer, while the anode resistance was invariant (∼0.4
Ω cm
2
). By developing a semi-empirical current–potential
model including an ion mass transport effect, we proved that the number
of holes in the cathode surface is the key to the maximal utilization
of the present anode. This eventually led to notable gains in the
maximum power density to 205 mW cm
–2
at 700 °C
in experiments. Lastly, a durability test was conducted to reconfirm
the effect of ionic mass transfer on the power generation over time.
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