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Metal particles, suspended as wear debris or as additives, have a major influence on lubrication technology. They are known mostly for negative roles, but even iron nanoparticles, which are likely to pass through most filters, have not yet been quantitatively evaluated for their effects on friction and wear. In this study iron and copper nanoparticle suspensions were formulated in high sulphur paraffinic mineral oils and food grade rapeseed oil. The suspension stabilisation mechanism based on steric repulsion appeared more effective than ionic repulsion principle. Iron nanoparticle suspensions were investigated using four ball antiwear tribotester. Iron nanoparticles did not show statistically significant effects on wear or friction in mineral oil suspension. However, addition of surfactants improved the tribological performance. Wear, friction and sample temperature data along with microscopy evaluation suggested that formation of protective films in the friction zone was the most likely reason for reduction of wear, average friction and the duration of break-in regime.

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Tribological properties of rapeseed oils manufactured and processed by different methods and modified by the anti-wear additives were analysed. Tribological tests presented that unrefined rapeseed oil has better wear resistance compared to refined oil. Modification of rapeseed oil with 2% of special biological anti-wear additives has the greatest influence on refined rapeseed oil. Chemical analysis shows that refinement removes acids from oil. Refinement and lower acidity allows more efficient operation of special biological anti-wear additives.

Purpose-The purpose of this paper is to conduct research on the possibility of improving the tribological and utilization properties of lard and rapeseed oil bio-based greases by mixing it with ethanol and selection of thickener and modification with special biological additives. Design/methodology/approach-Rapeseed oil-and lard-based greases with sodium and lithium soap thickeners were mixed with either water or ethanol and modified with a special biological anti-wear additive. Tribological properties of modified lubricants evaluated on a four-ball machine. Findings-Rapeseed oil-and lard-based greases suspended in ethanol and modified with bio-additive have the same wear resistance as the industrial non-biological lubrication grease and much higher wear resistance as bio-based reference grease. The tribological efficiency of the additives is higher in greases of rapeseed oil and less efficient in lard-based greases. Oxidation and wear tests show that investigated bio-based greases have comparatively stable tribological properties also after their aging. Modified greases have sufficient consistence according penetration measurements and high thermal resistance according drop-point temperature measurements. All produced experimental greases pass within the category of the easily degradable materials. Originality/value-The greases mixed with the ethanol make possible to form more homogeneous and stable grease mixture. Modified bio-based greases have significantly higher wear resistance as bio-based reference grease, their lubrication properties are stable also after the aging and are categorized as easily degradable materials.