The effects of gallia addition on the Pt dispersion and the activity for ethylene hydrogenation at 0°C were studied for Pt-supported catalysts as a function of the reduction temperature (350, 450, and 550°C). The catalysts contained 0.5 wt.% Pt and were prepared by successive incipient wetness impregnations with Ga(NO 3 ) 3 and H 2 PtCl 6 aqueous solutions. CO and H 2 chemisorption data indicated that, the addition of small amount of Ga 2 O 3 caused an increase of the Pt dispersion and a decrease of ethylene conversion. Both of them decreased appreciably when Ga 2 O 3 addition was increased, particularly, for the case where bGa 2 O 3 was used as a support. The increase in reduction temperature magnified the negative effects of the gallia addition on dispersion and activity, although the addition of small amount of gallia improved the resistance to metal sintering. Results were interpreted in terms of the presence of reduced Ga species, which can encapsulate Pt particles.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2025 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.