Here,
we report a facile hydrothermal synthesis method to prepare BiFeO3 nanowire-reduced graphene oxide (BFO-RGO) nanocomposites.
The unique properties of 2-D reduced graphene oxide (RGO) and 1-D
BiFeO3 nanowires (BFO) were exploited to design nanocomposites
to obtain high performing microwave absorber materials. The composite
with 97 wt % BFO and 3 wt % RGO exhibited minimum reflection loss
value of −28.68 dB at 10.68 GHz along with the effective absorption
bandwidth (≥ −10 dB) ranging from 9.6 to 11.7 GHz when
the absorber thickness was only 1.55 mm. First-principles calculations
based on density functional theory (DFT) of BFO, graphene, and BFO-RGO
nanocomposites were performed to obtain information about their electronic
structures to interpret their complex permittivity and its derived
properties. To the best of our knowledge, this is the first time investigations
on microwave absorption properties of the BiFeO3 nanowire
and BFO-RGO nanocomposites have been reported, and this nanocomposite
shows its potential to be used as a lightweight, high performing microwave
absorber in the X-band region.
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