Highly sensitive permeation measurements are crucial for the characterization and development of polymeric substrates for flexible display applications. In particular, organic light-emitting devices require substrates with extremely low permeation rates for water and oxygen. Here we demonstrate a concept for measuring ultralow permeation rates. The amount of oxidative degradation in a thin Ca sensor is monitored by in situ resistance measurements. The benefits of this technique are demonstrated for polyester foils with single- and double-sided barrier coatings. A sensitivity limit is imposed by the quality of the encapsulation. The resulting base line contribution to the water vapor transmission rate of a glass reference is below 10−6 g/m2 day at accelerated test conditions.

Organic light-emitting diodes were fabricated on a 125-μm-thick polyethylene terephthalate substrate covered with 100 nm indium tin oxide. The luminance–current–voltage performance and the emission spectrum of the devices are investigated in the bent state under mechanical stress at different bending radii. Down to a curvature of 15 mm, no significant decrease in the device performance is found compared to the relaxed state, as well as to conventional devices on glass substrates.

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Joule heating and its impact on the brightness homogeneity are investigated since the luminance distribution is a key issue in large area organic light emitting diodes. In addition to previous reports, it is also important to consider the device temperature as a main factor for determining the luminance homogeneity. At a luminance of 1000cd∕m2 the active area reaches an average temperature of 40.6°C and a peak of 46.2°C. The increased device temperature is leading to higher local current densities resulting in a reduced brightness homogeneity. Modeling confirms these results and can be used for further device layout optimization.

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