Alumina nanofibers containing either platinum or rhodium crystalline nanoparticles have been successfully fabricated by electrospinning a solution of polyvinylpyrrolidone mixed with platinum or rhodium chloride and subsequent calcination and hydrogen reduction. Transmission electron microscopy images indicate that the platinum and rhodium nanoparticles are well dispersed on the electrospun alumina nanofibers. X-ray diffraction results demonstrate that the platinum and rhodium nanoparticles are crystalline, while the alumina matrix is amorphous. Furthermore, X-ray photoelectron spectroscopy was used to investigate the chemical nature of these nanofibers containing noble metals before and after calcination and hydrogen processing.

Local oxidation of metal, semiconductor, and polymer surfaces has provided a common basis from which to explore fundamental principles of nanolithography and prototype functional nanostructures for many years now. This article summarizes an investigation of local oxidation for iron and Group IV metal thin films using both scanning probe microscopy and high-voltage nanoimprinting methods. We illustrate how the underlying kinetics of metal oxidation in the presence of nitrogen, which is incorporated into the metal film during the growth process, is dramatically enhanced compared with that of single-crystal silicon. We then go on to demonstrate subsequent selective etching of latent features and a potential magnetic application.