As the world is heading towards a sustainable future, it is highly important to develop low-cost electrocatalysts for energy generation devices. Herein, we report the synthesis of iron-carbon hybrid (C@Fe3C/Fe3O4) nanocomposite for oxygen reduction reaction (ORR), synthesized using bagasse as a carbon source material and Fe(III) precursor at 900 ˚C. The synthesized C@Fe3C/Fe3O4 composite exhibits a high surface area of ~930 m 2 /g. The electrode material has a 0.86 V overpotential vs RHE. Moreover, the electrocatalyst shows catalytic stability upto 18 h at the static potential of 0.25 V vs RHE at the rotation speed of 1600 rpm. Herein, the electron transfer number is close to 4 which suggests that our electrocatalyst may have an impact on efficient electrocatalyst designing for ORR in alkaline solution.
As the world is heading towards a sustainable future, it is highly important to develop low-cost electrocatalysts for energy generation devices. Herein, we report the synthesis of iron-carbon hybrid (C@Fe3C/Fe3O4) nanocomposite for oxygen reduction reaction (ORR), synthesized using bagasse as a carbon source material and Fe(III) precursor at 900 ˚C. The synthesized C@Fe3C/Fe3O4 composite exhibits a high surface area of ~930 m2/g. The electrode material has a 0.86 V overpotential vs RHE. Moreover, the electrocatalyst shows catalytic stability upto 18 h at the static potential of 0.25 V vs RHE at the rotation speed of 1600 rpm. Herein, the electron transfer number is close to 4 which suggests that our electrocatalyst may have an impact on efficient electrocatalyst designing for ORR in alkaline solution.
As the world is heading towards sustainable future, it is highly important to develop low-cost electrocatalysts for energy generation devices. Herein, we report synthesis of iron-carbon hybrid (C@Fe3C/Fe3O4) nanocomposite for oxygen reduction reaction (ORR), synthesized using bagasse as a carbon source material and Fe(III) precursor at 900 ˚C. The synthesized C@Fe3C/Fe3O4 composite exhibits a high surface area of ~930 m 2 /g. The electrode material has a 0.86 V overpotential vs RHE. Moreover, the electrocatalyst shows catalytic stability upto 44,000 s at the static potential of 0.25 V vs RHE at the rotation speed of 1600 rpm. Herein, the electron transfer number is calculated to be 3.76-3.94 which suggest that the electrocatalyst could catalyze ORR nearly through a 4 electron transfer process in alkaline solution.
As the world is heading towards sustainable future, it is highly important to develop low-cost electrocatalysts for energy generation devices. Herein, we report synthesis of iron-carbon hybrid (C@Fe3C/Fe3O4) nanocomposite for oxygen reduction reaction (ORR), synthesized using bagasse as a carbon source material and Fe(III) precursor at 900 ˚C. The synthesized C@Fe3C/Fe3O4 composite exhibits a high surface area of ~930 m2/g. The electrode material has a 0.86 V overpotential vs RHE. Moreover, the electrocatalyst shows catalytic stability upto 44,000 s at the static potential of 0.25 V vs RHE at the rotation speed of 1600 rpm. Herein, the electron transfer number is calculated to be 3.76-3.94 which suggest that the electrocatalyst could catalyze ORR nearly through a 4 electron transfer process in alkaline solution.
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