Parallel 1D semiconductor channels connected by a superconducting strip constitute the core platform in several recent quantum device proposals that rely, for example, on Andreev processes or topological effects. In order to realize these proposals, the actual material systems must have high crystalline purity, and the coupling between the different elements should be controllable in terms of their interfaces and geometry. A strategy for synthesizing double InAs nanowires by the vapor‐liquid‐solid mechanism using III‐V molecular beam epitaxy is presented. A superconducting layer is deposited onto nanowires without breaking the vacuum, ensuring pristine interfaces between the superconductor and the two semiconductor nanowires. The method allows for a high yield of merged as well as separate parallel nanowires with full or half‐shell superconductor coatings. Their utility in complex quantum devices by electron transport measurements is demonstrated.
Parallel one-dimensional semiconductor channels connected by a superconducting strip constitute the core platform in several recent quantum device proposals that rely e.g. on Andreev processes or topological effects. In order to realize these proposals, the actual material systems must have high crystalline purity and the coupling between the different elements should be controllable in terms of their interfaces and geometry.We present a strategy for synthesizing double InAs nanowires by the vapor-liquid-solid mechanism using III-V molecular beam epitaxy. A superconducting layer is deposited onto nanowires without breaking vacuum, ensuring pristine interfaces between the superconductor and the two semiconductor nanowires. The method allows for a high
The dihydroazulene/vinylheptafulvene (DHA/VHF) photocouple is a promising candidate for molecular solar heat batteries, storing and releasing energy in a closed cycle. Much work has been done on improving the energy storage capacity and the half-life of the high-energy isomer via substituent functionalization, but similarly important is keeping these improved properties in common polar solvents, along with being soluble in these, which is tied to the dipole properties. However, the number of possible derivatives makes an overview of this combinatorial space impossible both for experimental work and traditional computational chemistry. Due to the time-consuming nature of running many thousands of computations, we look to machine learning, which bears the advantage that once a model has been trained, it can be used to rapidly estimate approximate values for the given system. Applying a convolutional neural network, we show that it is possible to reach good agreement with traditional computations on a scale that allows us to rapidly screen tens of thousands of the DHA/VHF photocouple, eliminating bad candidates and allowing computational resources to be directed toward meaningful compounds.
Unlocking the full potential of nanocrystals in electronic devices requires scalable and deterministic manufacturing techniques. A platform offering compelling paths to scalable production is microtomy, the technique of cutting thin lamellas with large areas containing embedded nanostructures. So far, this platform has not been used for the fabrication of electronic quantum devices. Here, microtomy is combined with vapor-liquid-solid growth of III/V nanowires to create a scalable platform that can deterministically transfer large arrays of single and fused nanocrystals-offering single unit control and free choice of the target substrate. Electronic devices are fabricated on cross-sectioned InAs nanowires with good yield, and their ability to exhibit quantum phenomena such as conductance quantization, single-electron charging, and wave interference are demonstrated. Finally, it is devised how the platform can host rationally designed semiconductor/superconductor networks relevant to emerging quantum technologies.
Unlocking the full potential of nanocrystals in electronic devices requires scalable and deterministic manufacturing techniques. A platform offering promising alternative paths to scalable production is microtomy, the technique of cutting thin lamellae with large areas containing embedded nanostructures. This platform has so far not been used for fabrication of electronic quantum devices. Here, we combine microtomy with vapor-liquid-solid growth of III/V nanowires to create a scalable platform that can deterministically transfer large arrays of single and fused nanocrystals -offering single unit control and free choice of target substrate. We fabricate electronic devices on cross-sectioned InAs nanowires with good yield and demonstrate their ability to exhibit quantum phenomena such as conductance quantization, single electron charging, and wave interference. Finally, we devise how the platform can host rationally designed semiconductor/superconductor networks relevant for emerging quantum technologies.
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