Due to its outstanding polarization properties and the possibility of lattice-matched growth on GaN, Sc x Al 1-x N is a promising material among group III nitrides providing a wide field of potential applications in modern semiconductor technology. However, epitaxial growth of Sc x Al 1-x N by MBE is still in an early stage of research. In this work, Sc x Al 1-x N samples were grown by plasma-assisted MBE on GaN-on-sapphire templates under a variety of growth conditions and pulsed supply of Sc and Al, resulting in compositions ranging from Sc 0.02 Al 0.98 N to Sc 0.69 Al 0.31 N. Samples grown in the highly metal-rich regime showed phase degradation and high surface roughness, whereas growth in the N-rich and intermediate regime led to phase purity and surface roughness as low as 0.7 nm. Electrical characterization revealed a 2DEG for Sc 0.2 Al 0.8 N with a sheet resistance of 215 Ω/□, a Hall mobility of 553 cm 2 V −1 •s −1 , and a sheet carrier density of 5.26 × 10 13 cm −2 at 77 K.
Crisis in coronavirus times requires understanding the effects on society and establishing efficient mechanisms to prevent infections. The disinfection of personal protection equipment by UVC light remains a key opportunity area. Therefore, this letter presents the main drawbacks and challenges on the fabrication of deep ultraviolet LEDs based on III-nitrides, such as the substrate selection, dislocation reduction, the increase of external quantum efficiency, enhancement of the radiative recombination in the active region, the complications to reach high Al content in AlGaN-based UVC LED avoiding the reduction of the p-doping, replacing the p-GaN contact layer by p-AlGaN without hindering the deposition of ohmic contacts. Furthermore, the cubic phase is suggested as a promising candidate for AlGaN UVC-LEDs applications as is discussed in this work.
A solar cell structure with a graded bandgap absorber layer based on InGaN has been proposed to overcome early predicted efficiency. Technological issues such as carrier concentration in the p- and n-type are based on the data available in the literature. The influence of carrier concentration-dependent mobility on the absorber layer has been studied, obtaining considerable improvements in efficiency and photocurrent density. Efficiency over the tandem solar cell theoretical limit has been reached. A current density of 52.95 mA/cm2, with an efficiency of over 85%, is determined for a PiN structure with an InGaN step-graded bandgap absorption layer and 65.44% of power conversion efficiency for the same structure considering piezoelectric polarization of fully-strained layers and interfaces with electron and hole surface recombination velocities of 10−3 cm/s.
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