Excess volumes, VE, of binary liquid mixtures of acrylonitrile with alkanols (Cl-C,o) have been determined by continuous dilution dilatometry at 308.15 K as a function of composition. The excess volumes are negative for acrylonitrile-methanol, both negative and positive for acrylonitrile-alkanols (C,-C,)and positive for acrylonitrile-alkanols (C6-Cl , , ) . The VE data have been analysed by graph theory. The graph-theoretical connectivity parameters of the third degree give information regarding the state of the species in the pure phase as well as in the mixture.
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