A selective microwave heating mechanism is reported that enables the synthesis of the metal–organic framework MIL-53(Al) on an unprecedented time-scale of 4.3 seconds.

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Demand for high purity silica used in component manufacture is set to outstrip current supply in the near future. As such, alternative processing routes to feed-stock materials suitable for use in lighting and solar cell fabrication are required, without having to rely on reject material from semi-conductor manufacture. In this work, we report a facile, environmentally friendly method of producing quartz powder with a total residual impurity level of 30 ± 3 ppm from whole pebbles having an initial impurity level of 158 ± 22 ppm. This has been achieved using a metallurgical upgrading process incorporating microwave pre-treatment, crushing and milling, High Intensity Wet Magnetic Separation (HIWMS) and acid leaching. This process yielded a quartz powder having an 80% reduction in residual impurities compared to the untreated quartz pebbles. Pre-treatment of whole quartz pebbles in a multimode microwave cavity for 10 minutes yielded a reduction of the residual elemental impurity content associated with micro-fluidic inclusion sites containing calcium, potassium and sodium of 84, 78, and 50 % respectively. Statistically significant reduction in residual aluminium phases was also observed (83%) compared to the as received material to below the IOTA® specification for Ultra High Pure Quartz produced by Sibleco. Mechanistically, this has been achieved by selectively heating impurity containing microfluidic inclusion sites. Resulting in their explosive decrepitation and enabling removal of the impurities in subsequent processing steps. It has been concluded that natural quartz pebbles can be upgraded through a combination of microwave treatment, magnetic and chemical refinement to produce a viable feedstock for the subsequent production of solar grade silicon.

Bioleaching (or microbial leaching) is a biohydrometallurgical technology that can be applied for metal recovery from anthropogenic waste streams. In particular, fly ashes and bottom ashes of municipal solid waste incineration (MSWI) can be used as a target material for biomining. Globally, approximately 46 million tonnes of MSWI ashes are produced annually. Currently landfilled or used as aggregate, these contain large amounts of marketable metals, equivalent to low-grade ores. There is opportunity to recover critical materials as the circular economy demands, using mesophile, moderately thermophile, and extremophile microorganisms for bioleaching. A Strengths, Weaknesses, Opportunities and Threats (SWOT) analysis was developed to assess the potential of this biotechnology to recover critical metals 2 from MSWI wastes. Bioleaching has potential as a sustainable technology for resource recovery and enhanced waste management. However, stakeholders can only reap the full benefits of bioleaching by addressing both the technical engineering challenges and regulatory requirements needed to realise and integrated approach to resource use.