Engineering apparatus that harness quantum theory promises to offer practical advantages over current technology. A fundamentally more powerful prospect is that such quantum technologies could out-perform any future iteration of their classical counterparts, no matter how well the attributes of those classical strategies can be improved. Here, for optical direct absorption measurement, we experimentally demonstrate such an instance of an absolute advantage per photon probe that is exposed to the absorbative sample. We use correlated intensity measurements of spontaneous parametric downconversion using a commercially available air-cooled CCD, a new estimator for data analysis and a high heralding efficiency photon-pair source. We show this enables improvement in the precision of measurement, per photon probe, beyond what is achievable with an ideal coherent state (a perfect laser) detected with 100% efficient and noiseless detection. We see this absolute improvement for up to 50% absorption, with a maximum observed factor of improvement of 1.46. This equates to around 32% reduction in the total number of photons traversing an optical sample, compared to any future direct optical absorption measurement using classical light.

Absorption spectroscopy is routinely used to characterise chemical and biological samples. For the state-of-the-art in laser absorption spectroscopy, precision is theoretically limited by shot-noise due to the fundamental Poisson-distribution of photon number in laser radiation. In practice, the shotnoise limit can only be achieved when all other sources of noise are eliminated. Here, we use wavelength-correlated and tuneable photon pairs to demonstrate how absorption spectroscopy can be performed with precision beyond the shot-noise limit and near the ultimate quantum limit by using the optimal probe for absorption measurement-single photons. We present a practically realisable scheme, which we characterise both the precision and accuracy of by measuring the response of a control feature. We demonstrate that the technique can successfully probe liquid samples and using two spectrally similar types of haemoglobin we show that obtaining a given precision in resolution requires fewer heralded single probe photons compared to using an idealised laser.

Harnessing the unique properties of quantum mechanics offers the possibility to deliver new technologies that can fundamentally outperform their classical counterparts. These technologies only deliver advantages when components operate with performance beyond specific thresholds. For optical quantum metrology, the biggest challenge that impacts on performance thresholds is optical loss. Here we demonstrate how including an optical delay and an optical switch in a feed-forward configuration with a stable and efficient correlated photon pair source reduces the detector efficiency required to enable quantum enhanced sensing down to the detection level of single photons. When the switch is active, we observe a factor of improvement in precision of 1.27 for transmission measurement on a per input photon basis, compared to the performance of a laser emitting an ideal coherent state and measured with the same detection efficiency as our setup. When the switch is inoperative, we observe no quantum advantage.Quantum mechanics quantifies the highest precision that is achievable in each type of optical measurement [1][2][3]. Single photon probes measured with single photon detectors are in principle optimal for gaining the most precision per-unit intensity when measuring optical transmission [4]. However, in practice, optical loss and low component efficiencies prevent an advantage from being achieved using single photon detectors [5]. One way to reduce the impact of lower component efficiency is to incorporate fast optical switching and an optical delay with schemes that are based on heralded generation of quantum sates [6]. This then enables use of a quantum state conditioned on the successful detection of a correlated signal -this is referred to as feed-forward.Feed-forward is key for demonstrations of optical quantum computing [7], it has been used in experiments that increase the generation rate [8][9][10][11][12] and signal-to-noise ratio [13] of heralded single photons, it has been used to calibrate single photon detectors [14] and it has also been applied to gather evidence of single photon sensitivity in animal vision [15]. Jakeman and Rarity proposed in Ref.[6] using feed-forward with correlated photon pairs to enable sub shot noise optical transmission measurements when component efficiency is otherwise not sufficient to permit a quantum advantage in passive direct detection [16][17][18]. But despite becoming identified as key to more general multi-photon entangled quantum state engineering for quantum metrology [19,20], feed-forward has not been implemented for quantum enhanced parameter estimation. Here we implement the proposal featured in Ref.[6] (Fig. 1) to realise sub shot noise measurement of transmissitivity, using single photon detectors that are too low in efficiency to enable sub shot noise performance in a passive measurement.The transmissivity η of a sample is in general estimated by measuring the reduction of light intensity from a known mean input valueN in , to a reduced mean valueN out according ...