The C13-norisoprenoid
aroma compounds 1,1,6-trimethyl-1,2-dihydronaphthalene
(TDN) and biosynthetically related vitispirane (VS) are important
contributors to the varietal aroma of Riesling wines and are released
from glycosidically bound carotenoid breakdown products during bottle
aging. TDN is appreciated by numerous winemakers, particularly in
aged Riesling wines. Higher levels of TDN, however, are perceived
as a “petrol” off-flavor, which is expected to increase
due to ongoing climate change. Wines produced from the same Riesling
clone, which was grafted on six different rootstocks, varied significantly
throughout two vintages in respect to their concentrations of free
and bound TDN and VS as well as other volatiles. Over three vintages,
the same compounds differed significantly among wines made from eight
Riesling clones grafted on the same rootstock. Genetically determined
loose grape clusters favored the formation of TDN and yielded wines
of stronger sensory petrol intensity. Berry size, however, had no
relevant impact on TDN and VS formation.
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