The structural composition of soil organic matter (SOM) was determined in twenty-seven soils with different vegetation from several ecological zones of Australia and Pakistan using solid-state CPMAS 13 C NMR. The SOM was characterized using carbon types derived from the NMR spectra. Relationships were determined between K oc (sorption per unit organic C) of carbaryl (1-naphthyl methylcarbamate) and phosalone (S-6-chloro-2,3-dihydro-2-oxobenzoxazol-3-ylmethyl O,O-diethyl phosphorodithioate) and the nature of organic matter in the soils. Substantial variations were revealed in the structural composition of organic matter in the soils studied. The variations in K oc values of the pesticides observed for the soils could be explained only when variations in the aromatic components of SOM were taken into consideration. The highly significant positive correlations of aromaticity of SOM and K oc values of carbaryl and phosalone revealed that the aromatic component of SOM is a good predictor of a soil's ability to bind such nonionic pesticides.
Selection by herbicides has resulted in widespread evolution of herbicide resistance in agricultural weeds. In California, resistance to glyphosate was first confirmed in rigid ryegrass in 1998. Objectives of this study were to determine the current distribution and level of glyphosate resistance in Italian ryegrass, and to assess whether resistance could be due to an altered target site. Seeds were sampled from 118 populations and seedlings were treated with glyphosate at 866 g ae ha−1. Percentage of survivors ranged from 5 to 95% in 54 populations. All plants from 64 populations died. One susceptible (S) population, four putatively resistant (R) populations, and one S accession from Oregon were used for pot dose–response experiments, shikimic acid analyses, and DNA sequencing. Seedlings were treated with glyphosate at eight rates, ranging from 108 to 13,856 g ae ha−1. Shoot biomass was evaluated 3 wk after treatment and fit to a log-logistic regression equation. On the basis of GR50(herbicide rate required to reduce growth by 50%) values, seedlings from putatively R populations were roughly two to 15 times more resistant to glyphosate than S plants. Shikimic acid accumulation was similar in all plants before glyphosate treatment, but at 4 and 7 DAT, S plants from California and Oregon accumulated approximately two and three times more shikimic acid, respectively, than R plants. Sequencing of a cDNA fragment of the EPSPS coding region revealed two different codons, both of which encode proline at amino acid position 106 in S individuals. In contrast, all R plants sequenced exhibited missense mutations at site 106. Plants from one population revealed a mutation resulting in a proline to serine substitution. Plants from three R populations exhibited a mutation corresponding to replacement of proline with alanine. Our results indicate that glyphosate resistance is widespread in Italian ryegrass populations of California, and that resistance is likely due to an altered target enzyme.
Uncertainty in climatic and weather conditions may result in lodging. Lodging is a most chronic constraint, which is causing tremendous yield reduction in crop plants; therefore, better understanding to control lodging-induced adversities or to enhance lodging resistance in cereals is imperative. In this review, we presented a contemporary synthesis of the existing data regarding the effects of lodging on growth and yield of cereals. Moreover, we highlighted key factors which trigger the detrimental effects of lodging in cereals. Numerous morphological, anatomical, and biochemical traits in plants that can influence lodging risk have also been discussed. These traits showed significant correlation with lodging resistance in cereals. At end, we tried to link our hypothetical concepts with previous evidences and provided a comprehensive summary of all the possible management approaches that can be used to further control lodging effects on cereals. The selection of a management option though is based on cereal type and genotype; nonetheless, different agronomic approaches including seeding rate, sowing time, tillage system, crop rotation, and fertilizer application help in reducing lodging risk in cereals.
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