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C5F10O has been widely studied as a promising environmentally friendly substitute to SF6 in power equipment. Up to now, the environmentally friendly gas insulated equipment developed still uses the same sealing materials as SF6 gas insulation equipment. However, whether these sealing materials are chronically compatible with C5F10O has always been a fundamental problem that perplexes the industry and academia. In this study, a thermally accelerated aging experiment on four rubber materials contacted with C5F10O/N2 was carried out. During the experiment, aged rubbers were analyzed using scanning electron microscopy and x-ray photoelectron spectroscopy to obtain the surface morphology characteristic and element composition. The gas samples were collected periodically and detected through gas chromatography mass spectrometry. Meanwhile, the degradation of the rubbers’ mechanical property is tested to figure out their long-term compatibility with C5F10O/N2 mixtures. Surface analysis of the rubber samples showed that after thermal accelerated aging, F in the form of C–F bonding and metal fluorides were detected on the surface of the ethylene propylene diene monomer (EPDM), nitrile butadiene rubber (NBR), chloroprene rubber (CR), and methyl vinyl silicone rubber (VMQ), which did not exist in origin samples. The main gaseous decomposition products of C5F10O include CO, CO2, C3F6, and C3F7H, and the concentration when coexisting with rubber is significantly higher than that in the control group. The compression performance of aged rubbers all reduced, and the compression performance of EPDM and NBR is better than that of CR and VMQ. The experimental results proved the incompatibility between C5F10O and these four rubbers, while EPDM and NBR showed less deterioration in compression properties and could be more suitable for the C5F10O power equipment.

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