Manipulated images and videos have become increasingly realistic due to the tremendous progress of deep convolutional neural networks (CNNs). While technically intriguing, such progress raises a number of social concerns related to the advent and spread of fake information and fake news. Such concerns necessitate the introduction of robust and reliable methods for fake image and video detection. Toward this in this work, we study the ability of state-of-the-art video CNNs including 3D ResNet, 3D ResNeXt, and I3D in detecting manipulated videos. In addition, and toward a more robust detection, we investigate the effectiveness of attention mechanisms in this context. Such mechanisms are introduced in CNN architectures in order to ensure that robust features are being learnt. We test two attention mechanisms, namely SE-block and Non-local networks. We present related experimental results on videos tampered by four manipulation techniques, as included in the FaceForensics++ dataset. We investigate three scenarios, where the networks are trained to detect (a) all manipulated videos, (b) each manipulation technique individually, as well as (c) the veracity of videos pertaining to manipulation techniques not included in the train set.
In the present article we have demonstrated the effectiveness
of
optimally tuned range-separated hybrid (RSH) functional to determine
the electronic transitions from two fluorophore moieties (blue and
yellow/orange) within a single white light emitter (WLE). First, the
optimally tuned range separation parameter (ω) is calculated
for two white emitting fluorophores (W1 and W2) already reported in
the literature. The success of the optimally tuned RSH functional
ω*B97XD, used in the TDDFT study, encouraged the authors to
design eight new single organic white light emitters with frustrated
energy transfer between the two individual fluorophore moieties (blue
and yellow/orange). The simulated spectra (the band shapes, to be
more specific) generated by TDDFT study and outcomes through natural
transition orbital (NTO) and natural bond orbital (NBO) studies clearly
demonstrate that all the designed eight organic molecules are potential
white light emitters and can be synthesized in future.
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