A simple approach was developed to prepare carboxycellulose nanofibers directly from untreated biomass using nitric acid or nitric acid-sodium nitrite mixtures. Experiments indicated that this approach greatly reduced the need for multichemicals, and offered significant benefits in lowering the consumption of water and electric energy, when compared with conventional multiple-step processes at bench scale (e.g., TEMPO oxidation). Additionally, the effluent produced by this approach could be efficaciously neutralized using base to produce nitrogen-rich salts as fertilizers. TEM measurements of resulting nanofibers from different biomasses, possessed dimensions in the range of 190-370 and 4-5 nm, having PDI = 0.29-0.38. These nanofibers exhibited lower crystallinity than untreated jute fibers as determined by TEM diffraction, WAXD and C CPMAS NMR (e.g., WAXD crystallinity index was ∼35% for nanofibers vs 62% for jute). Nanofibers with low crystallinity were found to be effective for removal of heavy metal ions for drinking water purification.
Enzymes are also known natural catalysts. Lipases are flexible enzymes that are mostly used. These enzymes are found extensively all over the animal and plant kingdoms, likewise in molds and bacteria. Among all identified enzymes, lipases have concerned the mainly biotechnological attention. This review paper discusses the characteristic, microbial origin and application of lipases. The present review discussed about different characteristics and sources (fungal, bacteria's) of lipase. The present article also discussed about different bioreactors used for lipase production and different biotechnological applications (food, detergent, paper and pulp, biofuels etc) of lipases. An observation to considerate lipases and their applications as bulk enzymes and high-value of production, these enzymes are having huge impact in different bioprocesses.
In this study, anionic dialdehyde cellulose (DAC) and
cationic
dialdehyde cellulose (c-DAC) nanofibrous adsorbents were prepared
via a two-step reaction from bamboo pulp, using sodium periodate and
Girard’s reagent T as oxidizing and cationizing agents, respectively.
The performance of DAC and c-DAC for selective dye adsorption and
separation was evaluated by six different organic dyes (with varying
charge properties) and certain binary mixtures. Both adsorbents could
remove the dyes but with different capability, where DAC exhibited
high adsorption efficiency against cationic dyes (e.g., the maximum
adsorption capacity for Bismarck brown Y was 552.1 mg/g) and c-DAC
exhibited high adsorption efficiency against anionic dyes (e.g., the
maximum adsorption capacity for Congo red was 540.3 mg/g). To investigate
the adsorption mechanism for these adsorbents, effects of contact
time, initial pH value, initial dye concentration, and ionic strength
on the adsorption activity against Congo red were investigated. The
adsorption equilibrium data of DAC were found to fit best with the
Langmuir isotherm model, whereas that of c-DAC were found to fit best
with the Freundlich model. Both DAC and c-DAC adsorption kinetic data
could be described by the pseudo-second-order kinetic model, and these
adsorbents possessed stable adsorption efficiency in the pH range
of 4–10. Furthermore, their dye adsorption capabilities were
found to increase with increasing ionic strength (salt concentration).
The distinctive complementary features of DAC and c-DAC will allow
them to remove a wide range of organic dyes from industrial wastewater.
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