Drinking water treatment residuals (DWTRs) generated during drinking water treatment have been proposed for use in lake restoration as a solid-phase sorbent to inactivate phosphorus (P) in lake sediment. However, treatments that minimize leaching of nitrogen (N) and optimize P sorption capacity may be necessary prior to use. This study assessed seven different treatment methods, including washing and heat treatments at different temperatures and with and without oxygen limitation, among two DWTRs from Thailand. Results showed that oxygen-limited heat treatment at 600 °C substantially reduced N leaching (<0.2 mg/kg TKN) while also improving P sorption capacity (increase of 18–32% compared to untreated DWTR) to a maximum of 45.7 mg P/kg. Washing with deionized water reduced N leaching if a sufficient volume was used but did not improve P sorption. Heating at 200 °C with or without the presence of oxygen did not improve N leaching or P sorption. Regression of P sorption parameters from a two-surface Langmuir isotherm against physio-chemical properties indicated that oxalate-extractable (i.e., amorphous) aluminum and iron were significantly associated with total P sorption capacity (R2 = 0.94), but micropores and oxalate-extractable P modulated the P sorption from high-affinity to low-affinity mechanisms. In conclusion, this study confirmed the importance of amorphous aluminum in DWTRs for inactivating P, and the results suggest that high-temperature treatment under oxygen-limited conditions may be the most reliable way to optimize DWTRs for environmental remediation applications.
The Wet Bulb Globe Temperature (WBGT) index is a standard for assessing environmental heat stress, but the requirement of expensive instrument with specialized maintenance is limited its use. This study aims to develop the empirical equation to estimate the WBGT from Heat Index (HI) calculated from portable temperature and humidity recorder (THR), based on the data collected at seven sites covering all regions of Thailand. Comparative analysis shows that the HI values calculated from THR (HITHR) are consistent well with those measured from the thermal environmental monitor (HIQT36) as evidenced by a highly positive correlation between them (r=0.97; p<0.01; n=4,303). These results suggest high reliability of the portable THR and its acceptance to be used instead of the standard QT36 device. Based on a simple linear regression developed to estimate WBGT from the HITHR, it was found that the model accounts for at least 90% of the variance of the observed WBGT (dependent variable). In addition, validation of the model with the statistical methods shows relatively small errors of the estimated WBGT values in comparison to the observed values. With this evidence, the developed empirical regression equation can be used to estimate WBGT with high accuracy and confidence. Simple and easier to use for the practitioners who are involved in public health works at community level, a heat monitoring tool kit consisting of a THR, WBGT chart and recommended actions were further developed based on the results obtained. This tool kit is a low-cost and simple device which can be used by various community-level stakeholders to prevent and reduce heat injuries and deaths of risk groups, especially the elderly. This tool is necessary in light of anthropogenic-induced warming and Thailand’s aging society.
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