The presented data shows how cornstarch can be modified to a material that can effectively remove organics pollutants from a real wastewater. A low-cost adsorbent obtained from cornstarch by the crosslinking with epichlorohydrin. The prepared crossed linked starch (CLS) adsorbent characterized by X-ray diffraction, zeta potential, Fourier-transform infrared spectroscopy, atomic force microscopy, scanning electron microscopy, and Brunauer–Emmett–Teller surface area. The effects of initial chemical oxygen demand of the real wastewater, temperature and time of the adsorption of the organics on the prepared CLS were analyzed. The removal of the highest organics concentration was 89.85%. Langmuir and Freundlich isotherm models have been applied to investigate the adsorption equilibrium. The maximum adsorption capacity of the organics pollutants on the prepared CLS was 256.41 mg/g. Thermodynamic parameters show that the adsorption process of organics on CLS is more favorable at low temperature.
This research investigates the adsorption isotherm and adsorption kinetics of nitrogen from air using packed bed of Li-LSX zeolite to get medical oxygen. Experiments were carried out to estimate the produced oxygen purity under different operating conditions: input pressure of 0.5 – 2.5 bar, feed flow rate of air of 2 – 10 L.min-1 and packing height of 9-16 cm. The adsorption isotherm was studied at the best conditions of input pressure of 2.5 bar, the height of packing 16 cm, and flow rate 6 Lmin-1 at ambient temperature, at these conditions the highest purity of oxygen by this system 73.15 vol % of outlet gas was produced. Langmuir isotherm was the best models representing the experimental data., and the model parameters were the maximum monolayer coverage (qm) 200 mg. g-1 and Kl 0.00234 L.mg -1. Also, from the Freundlich isotherm model, the sorption intensity (n) indicated favorable sorption of 1.435. The average free energy estimated from the DRK isotherm model was 0.02 KJ.mol-1, which proved the adsorption process to follow physical nature. The results got from experiments showed a coincidence to the pseudo-first-order kinetic model.
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