Onsite screening of volatile organic compounds in water, soil, and vapor matrices using portable gas chromatographs equipped with photoionization detectors has become an increasingly popular technique in hydrologic investigations. To be most effective, the proper equipment is required and the operator needs to be adequately trained. Because of changing environmental conditions, onsite operation of a gas chromatograph requires a rigorous instrumental protocol in order to ensure the quality of data produced. This report describes such a protocol.

Tertiary-treated wastewater currently (1991) is being injected into the Hueco bolson aquifer at a site in northeastern El Paso, Texas, to supplement the quantity of available freshwater. Hydrologic data were compiled and water-quality and bacterial data were collected from existing wells near the Hueco Bolson Recharge Project (HBRP) in August and September 1990 and 1991. Borehole tracer tests indicated upward groundwater flow in nearly all tested intervals of several observation wells. The cumulative volume of injected water was less than the volume produced from wells adjacent to the HBRP area. Water levels in three production wells, located more than 1.5 miles from the injection wells, declined at rates comparable to those observed before injection operations. Water levels in wells located within 0.75 mile of the injection-well pipeline declined at a slower rate after HBRP injection operations had begun. Between 1985 and 1991, water levels in observation wells located within 700 feet of an injection well either did not appreciably decline, or declined at smaller rates than water levels in more distant production wells. Trihalomethane compounds were detected in water from 8 of the 16 observation and production wells sampled in 1990 and in 10 of the 17 wells sampled in 1991. Concentrations of trihalomethane compounds in these samples ranged from 0.05 to 1.9 |lg/L (micrograms per liter) in 1990 and from 0.05 to 1.4 |ig/L in 1991. Concentrations of trihalomethane compounds in samples of injected water from two wells were 27.8 and 34.6 |J,g/L respectively, in 1991. Dibromomethane and dichloromethane were detected in water from injection wells and from observation wells within about 700 feet of the injection wells. Aerobic bacteria were determined to be the only bacteria type present in ground water except for samples from two wells, which also contained denitrifying bacteria. The populations of aerobic bacteria determined in ground water ranged from 80 to more than 160,000 most probable number of organisms per milliliter of sample.

Twenty-two bottom-sediment samples were collected from Town Lake in Austin, Texas, in 1991 and 1992 and analyzed for chlorinated insecticides by a reconnaissance-quality, electron-capture gas chromatography screening method developed by the U.S. Geological Survey (USGS). Four different chlorinated insecticides (aldrin, chlordane, dieldrin, and p,p'-DDT) and two degradation products of p,p'-DDT (p,p'-DDD and p,p'-DDE) were detected in these samples. The most significant insecticides detected were chlordane, which was detected in 20 of the 22 samples at concentrations that ranged from 26 to 140 micrograms per kilogram, and p,p'-DDT, which was detected in all 22 samples at concentrations that ranged from 5 to 40 micrograms per kilogram. Degradation products of p,p'-DDT were detected in all 22 samples. Concentrations of p,p'-DDD ranged from not detected to 117 micrograms per kilogram and for p,p'-DDE from 9 to 97 micrograms per kilogram. Of the 22 samples collected, 15 also were analyzed by the standard USGS laboratory analytical method for chlorinated insecticides to determine the comparability of the two methods. Correlation coefficients were calculated for chlordane (0.8662), p,p'-DDT (0.6393), p,p'-DDD (0.9401), p,p'-DDE (0.8595), and dieldrin (0.3819). A paired sign test at the 95 percent confidence level showed no significant difference between the screening method and the laboratory analytical method for all detected insecticides except aldrin. P-values were calculated from the data for chlordane (1.0000), p,p'-DDT (0.1796), p,p'-DDD (1.0000), p,p'-DDE (0.1796), and dieldrin (0.2891).

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