We analyze the high-electric-field technique designed by Yokoyama and van Sprang ͓J. Appl. Phys. 57, 4520 ͑1985͔͒ to determine the polar anchoring coefficient W of a nematic liquid crystal-solid substrate. The technique implies simultaneous measurement of the optical phase retardation and capacitance as functions of the applied voltage well above the threshold of the Frederiks transition.We develop a generalized model that allows for the determination of W for tilted director orientation. Furthermore, the model results in a new high-field technique, ͑referred to as the RV technique͒, based on the measurement of retardation versus applied voltage. W is determined from a simple linear fit over a well-specified voltage window. No capacitance measurements are needed to determine W when the dielectric constants of the liquid crystal are known. We analyze the validity of the Yokoyama-van Sprang ͑YvS͒ and RV techniques and show that experimental data in real cells often do not follow the theoretical curves. The reason is that the director distribution is inhomogeneous in the plane of the bounding plates, while the theory assumes that the director is not distorted in this plane. This discrepancy can greatly modify the fitted value of 1/W, and even change its sign, thus making the determination of W meaningless. We suggest a protocol that allows one to check if the cell can be used to measure W by the YvS or RV techniques. The protocol establishes new criteria that were absent in the original YvS procedure. The results are compared with other data on W, obtained by a threshold-field technique for the same nematic-substrate pair.
The popular “high-electric-field” technique to determine the polar anchoring coefficient W of a nematic–substrate interface requires the simultaneous measurement of the capacitance and optical phase retardation of a liquid crystal cell as a function of applied voltage. We develop a generalized model that makes it possible to eliminate the capacitance measurement. The new technique, called the RV (retardation versus voltage) technique, requires only the measurement of retardation as a function of applied voltage, and allows for the determination of W by a linear fit over a prescribed voltage window. The technique is not sensitive to uniformity of the cell thickness, does not require patterned electrodes, and allows for the local probe of the surface. The value of W obtained by the RV technique is the same as W obtained by the traditional technique.
Elastic scattering of protons from Zr in the energy range E~= 9.8 to 135 MeV is analyzed using a dispersive optical model potential (OMP). In this analysis, a dispersion relation connects the volume integrals of the imaginary and the real parts of the OMP. Best-fit dispersive OMP parameters are obtained from fits to experimental cross section and analyzing power data at each energy, while the volume integrals of the imaginary potential and dispersive correction terms are fixed at the empirical values obtained in the individual proton elastic scattering analyses from 9.8 to 135 MeV. Predictions of the cross section and analyzing power angular distributions from the best-fit dispersive OMP and conventional OMP are obtained, and give similar quality fits to data. A dispersive OMP with parameters that show a smooth energy dependence are determined from fits to the entire data set. Comparison of cross sections and analyzing powers calculated by the dispersive OMP with experimental data at 160 and 185 MeV is also presented. The dispersive OMP with a smooth energy dependence is extended to the negative energy region with the guidance of the known first single-particle and single-hole state energies near the Fermi energy, EF = -6.8 MeV, to provide parameters for the shell model potential. This analysis also provides estimates for single-particle and hole energies E"», root-mean-square radii R"l,, expectation values of the effective mass (m */m ) "I,, occupation probabilities X"&,, absolute spectroscopic factors S"l,, and spectral functions g"&, (E") for proton single-particle and single-hole orbits in Zr. These estimates are compared with available experimental information.PACS number(s): 24. 10.Ht, 24.70.+s, 25.40.Cm
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