Robert de Levie scite author profile

The rate‐enhancing effect of some specifically adsorbed anions on the kinetics of several electrode reactions greatly exceeds that predicted by the Frumkin correction. The literature on this effect is critically reviewed, including Heyrovsky's 1947 hypothesis of ligand bridging and the pioneering work of Aikens and Ross on the oxidation of Cr(II). Two current theoretical interpretations are discussed and several related comments are made regarding ionic adsorption.

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Robert de Levie

On porous electrodes in electrolyte solutions

On porous electrodes in electrolyte solutions—IV

The influence of surface roughness of solid electrodes on electrochemical measurements

The dynamic double layer: Two-dimensional condensation at the mercury-water interface

Anion Bridging and Anion Electrocatalysis on Mercury

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